First example of a Sn-C bond cleaved product in the reaction of Ph3SnOSnPh3 with carboxylic acids.: 3D-supramolecular network formation in the X-ray crystal structure of [Ph2Sn(OH)OC(O)(Rf)]2, Rf=2,4,6-(CF3)3C6H2

被引:32
作者
Chandrasekhar, V [1 ]
Nagendran, S
Gopal, K
Steiner, A
Zacchini, S
机构
[1] Indian Inst Technol, Dept Chem, Kanpur 208016, Uttar Pradesh, India
[2] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England
关键词
D O I
10.1039/b212409b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A 1:2 reaction of Ph3SnOSnPh3 1 with RfCOOH 2 leads to the formation of [Ph2Sn(OH)OC(O)(R-f)](2) 3, by means of a facile Sn-C bond cleavage process.
引用
收藏
页码:862 / 863
页数:2
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