Nickel(II)-catalyzed asymmetric alkylation of acyclic oxocarbenium ions with carboxylic acid derivatives

被引：8

作者：

Ye, Pengbo ^{[1
]}

Liu, Xuan ^{[1
]}

Wang, Gang ^{[1
]}

Liu, Lei ^{[1
]}

机构：

[1] Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China

来源：

CHINESE CHEMICAL LETTERS | 2021年 / 32卷 / 03期

关键词：

Oxocarbenium ion; Acyclic; Nickel; Asymmetric catalysis; Alkylation; C-H ALKYNYLATION; ENANTIOSELECTIVE ADDITION; STEREOSELECTIVE-SYNTHESIS; CYCLIZATION; CATALYSIS; ALDEHYDES; ACETALS; ENOLATE;

D O I：

10.1016/j.cclet.2020.08.034

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A nickel(II)-catalyzed asymmetric alkylation of acyclic oxocarbenium ions generated in situ from corresponding acetals with carboxylic acid derivatives to prepare beta-alkoxyl carbonyl moieties with diverse alpha-substituents has been disclosed. The method exhibited broad scope of acetals and carboxylic acid derivatives with excellent enantioselectivity and good functional group compatibility, and can be conducted in a gram-scale without obvious loss of efficiency. (C) 2020 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.

引用

页码：1237 / 1240

页数：4

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