Nickel(II)-catalyzed asymmetric alkylation of acyclic oxocarbenium ions with carboxylic acid derivatives

被引：8
|
作者：
Ye, Pengbo [1 ]
Liu, Xuan [1 ]
Wang, Gang [1 ]
Liu, Lei [1 ]
机构：
[1] Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China
来源：
CHINESE CHEMICAL LETTERS | 2021年 / 32卷 / 03期
关键词：
Oxocarbenium ion; Acyclic; Nickel; Asymmetric catalysis; Alkylation; C-H ALKYNYLATION; ENANTIOSELECTIVE ADDITION; STEREOSELECTIVE-SYNTHESIS; CYCLIZATION; CATALYSIS; ALDEHYDES; ACETALS; ENOLATE;
D O I：
10.1016/j.cclet.2020.08.034
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A nickel(II)-catalyzed asymmetric alkylation of acyclic oxocarbenium ions generated in situ from corresponding acetals with carboxylic acid derivatives to prepare beta-alkoxyl carbonyl moieties with diverse alpha-substituents has been disclosed. The method exhibited broad scope of acetals and carboxylic acid derivatives with excellent enantioselectivity and good functional group compatibility, and can be conducted in a gram-scale without obvious loss of efficiency. (C) 2020 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码：1237 / 1240
页数：4
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