Aggregation and tautomeric properties of CI Acid Red 138

被引:19
作者
Iijima, T
Jojima, E
Antonov, L
Stoyanov, S
Stoyanova, T
机构
[1] Jissen Womens Univ, Dept Text Sci, Tokyo, Japan
[2] Natl Forestry Univ, Dept Ecol, Sofia 1756, Bulgaria
[3] Univ Sofia, Dept Chem, Sofia 1164, Bulgaria
基金
美国国家科学基金会;
关键词
CI Acid Red 138; tautomeric properties;
D O I
10.1016/S0143-7208(97)00042-9
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The spectral properties of CI Acid Red 138 and related dyes in respect of their azo(A)-hydrazone(H) tautomeric behavior were investigated. The observed influence of temperature and concentration was taken into account in the described theoretical model. The absorption spectra of the H-form and its corresponding H-dimer were calculated along with the structural parameters-the distance R between the molecules in the dimer (similar to 5.3 Angstrom) and the angle alpha between the transition dipole moments (similar to 56 degrees). (C) 1998 Elsevier Science Ltd.
引用
收藏
页码:81 / 92
页数:12
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