Reaction of nitric oxide with benzyl cyanide to yield a bis-diazeniumdiolated imidate

被引：14

作者：

Arnold, EV

Keefer, LK

Hrabie, JA ^{[1
]}

机构：

[1] NCI, Frederick Canc Res & Dev Ctr, Comparat Carcinogenesis Lab, Chem Sect, Frederick, MD 21702 USA

[2] NCI, Frederick Canc Res & Dev Ctr, SAIC Frederick, Frederick, MD 21702 USA

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 44期

关键词：

nitrogen oxides; nitriles; imidic acids and derivatives; diazenes;

D O I：

10.1016/S0040-4039(00)01535-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of nitric oxide with benzyl cyanide in the presence of sodium methoxide forms the bis-diazeniumdiolated imidate, PhC[C(OMe)=NH][N(O)NO-Na+](2). This compound decomposes in acidic media to yield nitric oxide, nitrous oxide and 2-oximino-2-phenylacetic acid methyl ester. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：8421 / 8424

页数：4

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