The cellulose aluminum oxide composite-supported imidazolium chloroaluminate ionic liquid as a novel and stable heterogeneous catalyst

被引:9
作者
Boroujeni, Kaveh Parvanak [1 ]
Tahani, Parisa [1 ]
机构
[1] Shahrekord Univ, Dept Chem, POB 88186-34141, Shahrekord, Iran
关键词
Cellulose-coated aluminum oxide; chloroaluminate ionic liquid; heterogeneous catalysis; 1,8-diox-ooctahydroxanthene; aldehyde; ULTRASOUND-ASSISTED SYNTHESIS; ONE-POT SYNTHESIS; 1,8-DIOXO-OCTAHYDROXANTHENE DERIVATIVES; XANTHENE DERIVATIVES; EFFICIENT SYNTHESIS; ACID; LEWIS;
D O I
10.1080/24701556.2017.1284103
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
1-Methyl-3-(triethoxysilylpropyl) imidazolium chloroaluminate ionic liquid anchored on a composite of cellulose and aluminum oxide was easily synthesized and tested for its catalytic activity in one-pot Knoevenagel condensation, Michael addition, and cyclodehydration of 5,5-dimethyl-1,3-cycloheanedione (dimedone) with aromatic aldehydes. The catalyst was characterized by Fourier transform infrared spectroscopy, thermal gravimetric analysis, scanning electron microscopy, energy-dispersive spectroscopy, elemental analysis, and atomic absorption technique. It is a non-hygroscopic (as a bench top catalyst), reusable, and environmentally compatible heterogeneous catalyst.
引用
收藏
页码:1150 / 1156
页数:7
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