An early-late heterobimetallic complex with an unsupported dative bond: synthesis and structure of [(Cy3P)2Pt-ZrCl4]

被引：44
作者：
Braunschweig, Holger [1 ]
Radacki, Krzysztof [1 ]
Schwab, Katrin [1 ]
机构：
[1] Julius Maximilians Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany
来源：
CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 06期
关键词：
TRIPODAL AMIDO LIGANDS; HIGHLY POLAR METAL; BLOCK METALS; REACTIVITY; PLATINUM; ZR/PD; NI;
D O I：
10.1039/b921608a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The presented platinum zirconium adduct [(Cy3P)(2)Pt-ZrCl4] expands the range of known platinum metal adducts towards early-late heterobimetallics displaying the first unsupported dative transition metal bond; X-ray structure and DFT calculations gave an estimation about the bond strength and indicate a strong Pt-Zr bond.
引用
收藏
页码：913 / 915
页数：3
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共 36 条
  • [1] [CP(2)TI(C-CTBU)(2)] AS AN ALKYNYL TRANSFER REAGENT - SYNTHESIS AND CHARACTERIZATION OF THE ASYMMETRICALLY BRIDGED HETERODIMETALLIC COMPLEX [CP(2)TI(C-CTBU)(2)PT(PPH(3))]CENTER-DOT-0.5 THF
    BERENGUER, JR
    FORNIES, J
    LALINDE, E
    MARTIN, A
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1994, 33 (20): : 2083 - 2085
  • [2] Structural characterization of heterodimetallic Zr/Pd and Zr/Rh catalyst precursors containing the C5H4PPh2 ligand
    Bosch, BE
    Brümmer, I
    Kunz, K
    Erker, G
    Fröhlich, R
    Kotila, S
    [J]. ORGANOMETALLICS, 2000, 19 (07) : 1255 - 1261
  • [3] Boron in the coordination spheres of three transition-metal atoms: Syntheses and structures of metalloborylenes stabilized by a transition-metal base
    Braunschweig, H
    Radacki, K
    Rais, D
    Seeler, F
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (07) : 1066 - 1069
  • [4] A boryl bridged complex:: An unusual coordination mode of the BR2 ligand
    Braunschweig, H
    Radacki, K
    Rais, D
    Whittell, GR
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (08) : 1192 - 1194
  • [5] Terminal borylene complexes stabilized by a transition-metal base
    Braunschweig, H
    Rais, D
    Uttinger, K
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (24) : 3763 - 3766
  • [6] Reactivity of Pt0 complexes toward gallium(III) halides:: Synthesis of a platinum gallane complex and oxidative addition of gallium halides to Pt0
    Braunschweig, Holger
    Gruss, Katrin
    Radacki, Krzysztof
    [J]. INORGANIC CHEMISTRY, 2008, 47 (19) : 8595 - 8597
  • [7] Interaction between d- and p-block metals: Synthesis and structure of platinum-alane adducts
    Braunschweig, Holger
    Gruss, Katrin
    Radacki, Krzysztof
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (41) : 7782 - 7784
  • [8] Molecular structure and cluster formation of a tert-butylborylene complex
    Braunschweig, Holger
    Burschka, Christian
    Burzler, Michael
    Metz, Stephanie
    Radacki, Krzysztof
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (26) : 4352 - 4355
  • [9] Complexes with Dative Bonds between d- and s-Block Metals: Synthesis and Structure of [(Cy3P)2Pt-Be(Cl)X] (X = Cl, Me)
    Braunschweig, Holger
    Gruss, Katrin
    Radacki, Krzysztof
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (23) : 4239 - 4241
  • [10] A quasi-covalent metal-metal bond in an early-late heterobimetallic Ti-Pt complex stabilized by phosphinoenolate ligands
    Braunstein, P
    Morise, X
    Bénard, M
    Rohmer, MM
    Welter, R
    [J]. CHEMICAL COMMUNICATIONS, 2003, (05) : 610 - 611
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