Silver-catalyzed decarboxylative acylation of arylglyoxylic acids with arylboronic acids

被引：30

作者：

Cheng, Kai ^{[1
]}

Zhao, Baoli ^{[1
]}

Qi, Chenze ^{[1
]}

机构：

[1] Shaoxing Univ, Zhejiang Key Lab Alternat Technol Fine Chem Proc, Shaoxing 312000, Peoples R China

来源：

RSC ADVANCES | 2014年 / 4卷 / 89期

基金：

中国国家自然科学基金;

关键词：

ALPHA-OXOCARBOXYLIC ACIDS; ALIPHATIC CARBOXYLIC-ACIDS; H BOND ACTIVATION; O-METHYL KETOXIMES; C-H; COUPLING REACTIONS; ROOM-TEMPERATURE; ORGANIC-CHEMISTRY; ELECTRON-TRANSFER; AQUEOUS-SOLUTION;

D O I：

10.1039/c4ra04361h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The silver-catalyzed coupling of arylboronic acids with arylglyoxylic acids was found to be an extremely efficient route for the synthesis of unsymmetrical diaryl ketones. It can be conducted on a gram scale under mild and open-flask conditions with good functional group compatibility, avoiding the addition of expensive and/or toxic metals.

引用

页码：48698 / 48702

页数：5

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