The first example of extended structure constructed from Knoth-type sandwich POMs and coordination fragments

被引：5
作者：
Wang, Guo-Wu [1 ,2 ,3 ]
Pan, Cheng-Ling [4 ]
Li, Ke-Chang [1 ,2 ]
Cui, Xiao-Bing [1 ,2 ]
Wang, Hai-Tao [3 ]
Wang, Yan [1 ,2 ]
Shi, Shu-Yun [1 ,2 ]
Xu, Ji-Qing [1 ,2 ]
机构：
[1] Jilin Univ, Coll Chem, Changchun, Jilin, Peoples R China
[2] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun, Jilin, Peoples R China
[3] NE Dianli Univ, Coll Chem, Jilin, Peoples R China
[4] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2010年 / 13卷 / 01期
关键词：
Polyoxometalate; Hydrothermal synthesis; Sandwich polyoxoanions; Knoth-type; POMs in extended structure; TRANSITION-METAL COMPLEX; MAGNETIC-PROPERTIES; CRYSTAL-STRUCTURE; BUILDING-BLOCKS; POLYOXOMETALATE; CLUSTERS; FRAMEWORK; HETEROPOLYANIONS; ARCHITECTURES; POLYMER;
D O I：
10.1016/j.inoche.2009.10.034
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel compound [P2W18M3O68][Cu(en)(2)](4)center dot 7H(2)O center dot 2OH(-) (M = 0.5W + 0.5Cu) 1 which contains the first example of extended structure constructed from Knoth-type sandwich polyoxoanions and transition metal coordination complexes has been hydrothermally synthesized and characterized by elemental analysis, IR spectrum, UV-Vis spectrum and single-crystal X-ray diffraction analysis. Crystal data for 1: triclinic, space group, P-1, a = 13.2718(7) angstrom, b = 13.6432(8) angstrom, c = 25.7307(15) angstrom, alpha = 104.7340(10)degrees, beta = 96.7630(10)degrees, gamma = 90.0330(10)degrees, V = 4472.2(4) angstrom(3), Z = 2. Structure solution and refinement based on 1090 parameters gave R1 (wR2) = 0.0409 (0.0993). (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码：116 / 118
页数：3
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