Microwave dielectric properties of (1-x)CeO2-xRE2O3 (RE = La, Nd, Sm, Eu, Gd, Dy, Er, Tm, Yb and Y) (0 ≤ x ≤ 1) ceramics

被引:31
作者
Anjana, Prabhakaran Sreekumari [1 ]
Joseph, Tony [1 ]
Sebastian, Mailadil Thomas [1 ]
机构
[1] CSIR, Natl Inst Interdisciplinary Sci & Technol, Mat & Minerals Div, Trivandrum 695019, Kerala, India
关键词
Solid state reactions; Microwave dielectric properties; Ceria; Rare earths; Solid solutions; HYDROTHERMAL SYNTHESIS; CERIA; OXIDE; RAMAN; ELECTROLYTES; CONDUCTIVITY; PR;
D O I
10.1016/j.jallcom.2009.09.057
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The (1 - x)CeO2-xRE(2)O(3) (RE = La, Nd, Sm, Eu, Gd, Dy, Er, Tm, Yb and Y) (0 <= x <= 1) ceramics have been prepared by solid state ceramic route. The solubility of different rare earths (RE) in ceria was investigated by using XRD, SEM and EDXA techniques. The microwave dielectric properties of the ceramics having different compositions were investigated. Several high Q dielectric resonator compositions were identified in (1 - x)CeO2-xRE(2)O(3) (RE = La, Nd, Sm, Eu, Gd, Dy, Er, Tm, Yb and Y), ceramics for 0 <= x <= 1. The best properties were obtained for 0.9CeO(2)-0.11 Eu2O3 (epsilon(r) = 25.4, Q(u) x f = 70,300 GHz, tau(f) = -64 ppm/degrees C), 0.8CeO(2)-0.2Dy(2)O(3) (epsilon(r) = 26.2, Q(u) x f = 70,150 GHz, tau(f) = -57 ppm/degrees C) and 0.3CeO(2)-0.7Sm(2)O(3) (epsilon(r) = 19.7, Q(u) x f = 79,450 GHz, tau(f) = -51 ppm/degrees C). (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:208 / 213
页数:6
相关论文
共 39 条
[1]   CeO2-Gd2O3 system: Unraveling of microscopic features by Raman spectroscopy [J].
Banerji, Ankita ;
Grover, Vinita ;
Sathe, Vasant ;
Deb, S. K. ;
Tyagi, A. K. .
SOLID STATE COMMUNICATIONS, 2009, 149 (39-40) :1689-1692
[2]   Preparation and properties of Gd3+ and Y3+ co-doped ceria-based electrolytes for intermediate temperature solid oxide fuel cells [J].
Guan, Xiangfeng ;
Zhou, Heping ;
Wang, Yanan ;
Zhang, Jun .
JOURNAL OF ALLOYS AND COMPOUNDS, 2008, 464 (1-2) :310-316
[3]   Structural characteristics and morphology of SmxCe1-xO2-x/2 thin films [J].
Hartmanova, M. ;
Jergel, M. ;
Mansilla, C. ;
Holgado, J. P. ;
Zemek, J. ;
Jurek, K. ;
Kundracik, F. .
APPLIED SURFACE SCIENCE, 2009, 255 (22) :9085-9091
[4]  
Hartridge A, 2001, J NANOPART RES, V3, P433
[5]   Ceria-based solid electrolytes - Review [J].
Inaba, H ;
Tagawa, H .
SOLID STATE IONICS, 1996, 83 (1-2) :1-16
[6]   STUDY OF A SOLID OXIDE FUEL-CELL WITH A CERIA-BASED SOLID ELECTROLYTE [J].
INOUE, T ;
SETOGUCHI, T ;
EGUCHI, K ;
ARAI, H .
SOLID STATE IONICS, 1989, 35 (3-4) :285-291
[7]   Lowering the sintering temperature of Gd-doped ceria by mechanochemical activation [J].
Jung, Won-Sik ;
Park, Hee-Seok ;
Kang, Young Jin ;
Yoon, Dang-Hyok .
CERAMICS INTERNATIONAL, 2010, 36 (01) :371-374
[8]  
KAJFEZ K, 1986, DIELECTRIC RESONATOR
[9]   Nano-sized ceria particles prepared by spray pyrolysis using polymeric precursor solution [J].
Kang, HS ;
Kang, YC ;
Koo, HY ;
Ju, SH ;
Kim, DY ;
Hong, SK ;
Sohn, JR ;
Jung, KY ;
Park, SB .
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2006, 127 (2-3) :99-104
[10]   The microwave dielectric properties of xTiO2(1-x)CeO2 ceramics [J].
Kim, DH ;
Lim, SK ;
An, C .
MATERIALS LETTERS, 2002, 52 (03) :240-243