Nickel(II) complex containing 5,5′-dimethyl-2,2′-bipyridine: Crystal structure and luminescent properties

被引：16

作者：

Abedi, A. ^{[1
]}

Saemian, E. ^{[1
]}

Amani, V. ^{[2
]}

机构：

[1] Islamic Azad Univ, Dept Chem, North Tehran Branch, POB 19585-936, Tehran, Iran

[2] Islamic Azad Univ, Dept Chem, Yadegar E Imam Khomeini RAH Branch, Tehran, Iran

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2015年 / 56卷 / 08期

关键词：

nickel(II); 5,5 '-dimethyl-2,2 '-bipyridine; crystal structure; luminescent properties; IRON(III) HETEROLIGAND COMPLEXES; PI STACKING INTERACTIONS; DIMETHYL-SULFOXIDE; SPECTROSCOPIC CHARACTERIZATION; X-RAY; CHLORIDE; 1,10-PHENANTHROLINE; 2,2'-BIPYRIDINE; DERIVATIVES; NETWORKS;

D O I：

10.1134/S0022476615080132

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[Ni(5,5'-dmbipy)(2)Cl-2]center dot 3H(2)O (1) complex was obtained from the reaction of NiCl2 center dot 6H(2)O with 5,5'-dimethyl-2,2'-bipyridine (5,5'-dmbipy) in a mixture of CH3OH/CH3CN. This complex was characterized by elemental analysis, IR, UV-Vis and luminescence spectroscopy, and its structure was determined by the single-crystal diffraction method. The Ni atom has a distorted octahedral coordination by four N atoms from two 5,5'-dmbipy ligands and two Cl- anions.

引用

页码：1545 / 1549

页数：5

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