A bimetallic oxide framework, [{Cu(bpy)}2Mo4O10(O3PCH2C6H4CH2PO3)2], constructed from novel {Mo4O10(O3PR)4}n4n- chains

被引：13

作者：

Jones, Stephanie ^{[1
]}

Liu, Hongxue ^{[2
]}

Schmidtke, Katherine ^{[1
]}

O'Connor, Charles C. ^{[2
]}

Zubieta, Jon ^{[1
]}

机构：

[1] Syracuse Univ, Dept Chem, Syracuse, NY 13244 USA

[2] Univ New Orleans, Coll Sci, Adv Mat Res Inst, New Orleans, LA 70148 USA

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2010年 / 13卷 / 02期

基金：

美国国家科学基金会;

关键词：

Bimetallic oxide; Copper-molybdophosphonate material; Organic-inorganic hybrid material; X-ray structure; METAL-ORGANIC FRAMEWORKS; ZEOLITIC IMIDAZOLATE FRAMEWORKS; STATE COORDINATION CHEMISTRY; MOLECULAR BUILDING-BLOCKS; HYDROGEN STORAGE; H-2; ADSORPTION; STRUCTURAL INFLUENCES; SURFACE MODIFICATION; RETICULAR SYNTHESIS; CARBON-DIOXIDE;

D O I：

10.1016/j.inoche.2009.12.008

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The hydrothermal reaction of Cu(CH3CO2)(2)center dot H2O, MoO3, 2,2'-bipyridine (bpy), and p-xylene diphosphonic acid in the presence of HF provided blue crystals of the bimetallic oxide phase [{Cu(bpy)}(2)Mo4O10(O3PCH2C6H4CH2PO3)(2)] (1). The three-dimensional structure of I is constructed from {Mo4O10(O3PR)(4)}(n)(4n-) chains, decorated with {Cu(bpy)}(2+) subunits and linked through the p-xylyl tether of the diphosphonate ligand. The molybdate building block within the chain is a tetranuclear {Mo4O10(O3P)(8)} cluster of edge- and corner-sharing {MoO6} Octahedra. Each phosphomolybdate chain is linked to four adjacent chains to generate the three-dimensional connectivity. Crystal data: C18H16CuMo2N2O11P2, fw = 753.69: monoclinic P2(1)/c, a = 7.9719(8) angstrom, b = 14.0392(14) angstrom, c = 21.274(2) angstrom, beta = 94.585(3)degrees. V = 2373.3(4) angstrom(3), Z = 4, D-calc = 2.109 g cm(-3), R-1 = 0.0610. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：298 / 301

页数：4

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