Ordered phase of platelike particles in concentrated dispersions

被引：96
作者：
Brown, ABD
Clarke, SM
Rennie, AR
机构：
[1] Univ London Birkbeck Coll, Dept Crystallog, Ind Mat Grp, London WC1E 7HX, England
[2] Univ Cambridge, Cavendish Lab, Cambridge CB3 0HE, England
来源：
LANGMUIR | 1998年 / 14卷 / 11期
关键词：
D O I：
10.1021/la971294d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The coexistence of two phases in concentrated dispersions of monodispersed platelike particles is reported. Small-angle neutron diffraction has been used to identify a highly ordered phase which coexists at equilibrium with a less ordered, less dense phase. The interparticle interactions were Varied by adjusting the salt concentration, and this influenced the concentration at which the phase transition occurred. Columnar or layer structures which could account for the observed diffraction pattern from the ordered phase are discussed.
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页码：3129 / 3132
页数：4
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