Di-(mu-pyrazolato-N:N')-bis[(2,2'-bipyridine-N,N')platinum(II)] bis(tetrafluoroborate) monohydrate

被引：12

作者：

Sakai, K ^{[1
]}

Sato, T ^{[1
]}

Tsubomura, T ^{[1
]}

Matsumoto, K ^{[1
]}

机构：

[1] WASEDA UNIV, DEPT CHEM, TOKYO 169, JAPAN

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 1996年 / 52卷

关键词：

D O I：

10.1107/S0108270195014326

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal structure of [Pt-2(C3H3N2)(2)(C10H8N2)(2)](BF4)(2).H2O, has been determined by X-ray diffraction. The six-membered ring consisting of the two Pt atoms and the four pyrazolyl N atoms has a boat-shaped conformation in which each Pt atom is located 1.14 (1) Angstrom above the plane defined by the four pyrazolyl N atoms. The two platinum coordination planes are canted at an angle of 77.9 (3)degrees, which is 8.1 (6)degrees smaller than the dihedral angle between the two bipyridyl planes. The dihedral angle between the two pyrazolyl planes is 83.4 (6)degrees. These angular strains are found to be caused by the intramolecular steric repulsion between the bipyridyl H and pyrazolyl N atoms.

引用

页码：783 / 786

页数：4

共 50 条

[41] Bis[iodo(N,N,N′,N",N"-pentamethyldiethyl-enetriamine-κ3N)platinum(II)] di-μ-iodo-bis[diiodoplatinate(II)]
Fanizzi, FP
Intini, FP
Maresca, L
Natile, G
Pacifico, C
[J]. ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 1999, 55 : 712 - 714
[42] Bis(4′-phenyl-2,2:6′,2′′-terpyridine- κ3 N, N′, N")copper(II) bis(tetrafluoroborate)
Toscano, RA
Martínez-Vargas, S
Valdés-Martínez, J
[J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : M846 - M848
[43] MECHANISM OF THE WATER-MEDIATED REDUCTION OF TRIS(2,2'-BIPYRIDINE-N,N')IRON(III), TRIS(2,2'-BIPYRIDINE-N,N')RUTHENIUM(III), AND TRIS(2,2'-BIPYRIDINE-N,N')OSMIUM(III) COMPLEXES
LAY, PA
SASSE, WHF
[J]. INORGANIC CHEMISTRY, 1985, 24 (26) : 4707 - 4710
[44] μ-oxalato-bis[(2,2′-bipyridine)(N,N-dimethylformamide)copper(II)] bis(perchlorate)
Zhang, GL
Li, YT
Wu, ZY
[J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : M1175 - M1177
[45] Bis(2,2′-bipyridine-κ2N,N′)chloridocobalt(II) perchlorate
Gao, Zhongjun
Li, Fahui
[J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M1664 - U1427
[46] Crystal structure of bis(2,2′-bipyridine-N,N′)dibromomanganese(II), MnBr2(C10H8N2)2
Hwang, In-Chul
Ha, Kwang
[J]. ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2007, 222 (03): : 209 - 210
[47] Crystal structure of bis(2,2′-bipyridine-N,N′)diiodomanganese(II), MnI2(C10H8N2)2
Ha, Kwang
[J]. ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2011, 226 (02): : 187 - +
[48] Bis(2,2′-bipyridine-κ2 N,N′)bis(4-hydroxybenzoato-κO)manganese(II)
Hu, ZQ
Wu, LB
Lai, GQ
[J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : M712 - M713
[49] {μ-N,N′-Bis[2-(dimethylamino)ethyl]oxamidato(2-)-κ6N,N′,O′:N",N"′,O}bis[(2,2′-bipyridine-κ2N,N′)copper(II)] bis(perchlorate)
Sun, Wei
Li, Yan-Tuan
Wu, Zhi-Yong
Zhang, Shu-Fang
Yin, Zhi-Wei
[J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2008, 64 (03) : M108 - M110
[50] Bis[μ-bis(diphenylphosphino)methane-κ2P:P′]bis[(2,2′-bipyridine-κ2N, N′)copper(I)] bis(tetrafluoroborate)
Jin, Shouwen
Wang, Daqi
[J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M1244 - +

← 1 2 3 4 5 →