A nonflammable lithium polymer battery with high performance for elevated temperature applications

被引:11
作者
Bakenov, Zhumabay [1 ]
Nakayama, Masanobu [1 ]
Wakihara, Masataka [1 ]
机构
[1] Tokyo Inst Technol, Dept Appl Chem, Meguro Ku, Tokyo 1528552, Japan
关键词
D O I
10.1149/1.2750229
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
All- solid Li/ LiFePO4 lithium polymer batteries with nonflammable poly (ethylene glycol) borate ester- based polymer electrolyte have been constructed and successfully operated at ambient and elevated temperatures. The cell exhibited about 90% of the theoretical capacity at 0.1 C rate at 60 degrees C. The AlPO4 addition to the polymer electrolyte improved the Li/ LiFePO4 polymer cell rate performance and allowed stable prolonged cycling even at 2 C rate at 60 degrees C. The ac impedance spectroscopy data showed the electrode/ electrolyte interface stabilization and lowering of cell impedance in the presence of AlPO4. (c) 2007 The Electrochemical Society.
引用
收藏
页码:A208 / A211
页数:4
相关论文
共 18 条
  • [1] Lithium extraction/insertion in LiFePO4:: an X-ray diffraction and Mossbauer spectroscopy study
    Andersson, AS
    Kalska, B
    Häggström, L
    Thomas, JO
    [J]. SOLID STATE IONICS, 2000, 130 (1-2) : 41 - 52
  • [2] Hot-pressed, solvent-free, nanocomposite, PEO-based electrolyte membranes II.: All solid-state Li/LiFePO4 polymer batteries
    Appetecchi, GB
    Hassoun, J
    Scrosati, B
    Croce, F
    Cassel, F
    Salomon, M
    [J]. JOURNAL OF POWER SOURCES, 2003, 124 (01) : 246 - 253
  • [3] Nanostructured materials for advanced energy conversion and storage devices
    Aricò, AS
    Bruce, P
    Scrosati, B
    Tarascon, JM
    Van Schalkwijk, W
    [J]. NATURE MATERIALS, 2005, 4 (05) : 366 - 377
  • [4] Versatile synthesis of carbon-rich LiFePO4 enhancing its electrochemical properties
    Bauer, EM
    Bellitto, C
    Pasquali, M
    Prosini, PP
    Righini, G
    [J]. ELECTROCHEMICAL AND SOLID STATE LETTERS, 2004, 7 (04) : A85 - A87
  • [5] Synthesis and performance of LiMn0.7Fe0.3PO4 cathode material for lithium ion batteries
    Chang, XY
    Wang, ZX
    Li, XH
    Zhang, L
    Guo, HJ
    Peng, WJ
    [J]. MATERIALS RESEARCH BULLETIN, 2005, 40 (09) : 1513 - 1520
  • [6] Reducing carbon in LiFePO4/C composite electrodes to maximize specific energy, volumetric energy, and tap density
    Chen, ZH
    Dahn, JR
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2002, 149 (09) : A1184 - A1189
  • [7] Polymer electrolyte plasticized with PEG-borate ester having high ionic conductivity and thermal stability
    Kato, Y
    Hasumi, K
    Yokoyama, S
    Yabe, T
    Ikuta, H
    Uchimoto, Y
    Wakihara, M
    [J]. SOLID STATE IONICS, 2002, 150 (3-4) : 355 - 361
  • [8] Thermally stable polymer electrolyte plasticized with PEG-borate ester for lithium secondary battery
    Kato, Y
    Yokoyama, S
    Ikuta, H
    Uchimoto, Y
    Wakihara, M
    [J]. ELECTROCHEMISTRY COMMUNICATIONS, 2001, 3 (03) : 128 - 130
  • [9] Stability of lithium polymer battery based on substituted spinel cathode and PEG-borate ester/PC plasticized polymer electrolyte
    Kottegoda, IRM
    Bakenov, Z
    Ikuta, H
    Wakihara, M
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2005, 152 (08) : A1533 - A1538
  • [10] Electrochemical performance of lithium polymer battery based on PC/polymer borate ester plasticizers
    Kottegoda, IRM
    Bakenov, Z
    Ikuta, H
    Uchimoto, Y
    Wakihara, M
    [J]. ELECTROCHEMICAL AND SOLID STATE LETTERS, 2005, 8 (01) : A30 - A33