Carbon dioxide capture in gallate-based metal-organic frameworks

被引:41
作者
Chen, Fuqiang [1 ]
Wang, Jiawei [1 ,3 ]
Guo, Lidong [1 ]
Huang, Xinlei [1 ]
Zhang, Zhiguo [1 ,2 ]
Yang, Qiwei [1 ,2 ]
Yang, Yiwen [1 ,2 ]
Ren, Qilong [1 ,2 ]
Bao, Zongbi [1 ,2 ]
机构
[1] Zhejiang Univ, Coll Chem & Biol Engn, Minist Educ, Key Lab Biomass Chem Engn, 38 Zheda Rd, Hangzhou 310027, Peoples R China
[2] Inst Zhejiang Univ Quzhou, 78 Jiuhua Blvd North, Quzhou 324000, Peoples R China
[3] Hangzhou Hangyang Co Ltd, Hangzhou 310014, Peoples R China
基金
中国国家自然科学基金;
关键词
Metal-organic frameworks; Carbon dioxide; Methane; Nitrogen; Adsorption separation; Molecular sieving; CO2; CAPTURE; ADSORPTION; CAPACITY; SELECTIVITY; NETWORKS; AFFINITY; POLYMER; BINDING; GAS;
D O I
10.1016/j.seppur.2022.121031
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Carbon capture and sequestration are vital industrial processes that not only mitigate the greenhouse effect but also promote upgrading of low-quality natural gas. Porous adsorbent-based adsorption separation process appeals to be promising, while it still remains a great challenge to develop adsorbents with high adsorption uptake and selectivity of CO2 as well as high working capacity in practical applications. In this work, a group of gallatebased metal-organic frameworks with aperture size of 3.52 to 3.65 angstrom were reported for molecular sieving of CO2 from N-2 and CH4. Remarkably, Mg-gallate exhibited a record-high uptake of CO2 (5.05 mmol g(-1)) among all reported molecular sieving adsorbents combined with ultrahigh uptake ratio of CO2/CH4 (29.7) and CO2/N-2 (84.2) at 1 bar and 298 K. Multiple O-H center dot center dot center dot C and O center dot center dot center dot H-O interactions afford dense packing of CO2 molecules in the framework structure with a density up to 1.06 g cm(-3) on Mg-gallate, verified by density function theory calculations. Experimental breakthrough experiments confirmed the superb separation performance of flue gas and natural gas over a wide range of temperature. Robust structure and cycling stability along with facile scaleup synthesis method further offer great potential of M-gallate in industrial applications.
引用
收藏
页数:8
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