KINETICS AND MECHANISM FOR THE OXIDATION OF ALKANES BY PEROXYNITROUS ACID IN THE GAS PHASE: THE SLOW STEP INVOLVING REACTION WITH OH RADICALS

被引：1

作者：

Lobachev, V. L. ^{[1
]}

Matvienko, Ya. V. ^{[1
]}

Rudakov, E. S. ^{[1
]}

机构：

[1] Natl Acad Sci Ukraine, LM Litvinenko Inst Phys Organ & Coal Chem, UA-83114 Donetsk, Ukraine

来源：

THEORETICAL AND EXPERIMENTAL CHEMISTRY | 2010年 / 46卷 / 02期

关键词：

alkanes; peroxynitrous acid; gas phase; kinetic distributive method; activation parameters; mechanism; hydroxyl radicals; CHEMISTRY;

D O I：

10.1007/s11237-010-9128-z

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A kinetic distributive method was used to determine the relative rate constants (k(RH)/k(EtH)) and activation parameters of reactions of alkanes (propane, butane, pentane, hexane, heptane, isobutane, cyclopentane, and cyclohexane) with peroxynitrous acid (HOONO) in the gas phase at 15-55 degrees C. The similarity of these results with the data for the reactions RH + center dot OH indicates that OH radicals are the active species in the reactions of HOONO with hydrocarbons.

引用

页码：119 / 125

页数：7

共 14 条

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