Fluorinated microporous organic polymers: design and applications in CO2 adsorption and conversion

被引：99

作者：

Yang, Zhen-Zhen ^{[1
]}

Zhao, Yanfei ^{[1
]}

Zhang, Hongye ^{[1
]}

Yu, Bo ^{[1
]}

Ma, Zhishuang ^{[1
]}

Ji, Guipeng ^{[1
]}

Liu, Zhimin ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Chem, Key Lab Colloid Interface & Thermodynam, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 90期

基金：

中国国家自然科学基金;

关键词：

CARBON-DIOXIDE CAPTURE; GAS-STORAGE; LINKED POLYMERS; PHENANTHROLINE; COMPLEXES;

D O I：

10.1039/c4cc06423b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Fluorinated microporous organic polymers (F-MOPs) were designed, showing twice higher CO2 adsorption capacity than corresponding non-fluorous MOPs. The incorporation of phenanthroline moieties into F-MOPs afforded them the ability to coordinate with Ag(I), and the resultant F-MOP-Ag(I) displayed high efficiency for the reaction of CO2 with propargyl alcohols to form alpha-alkylidene cyclic carbonates at 25 degrees C.

引用

页码：13910 / 13913

页数：4

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