Neutral and zwitterionic group 4 metal alkyls with ancillary boroxide ligands

被引：10
|
作者：
Cole, SC [1 ]
Coles, MP [1 ]
Hitchcock, PB [1 ]
机构：
[1] Univ Sussex, Dept Chem, Brighton BN1 9QJ, E Sussex, England
来源：
DALTON TRANSACTIONS | 2004年 / 21期
关键词：
D O I：
10.1039/b414155e
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The boroxide anion, [OB(mes)(2)](-), has been applied as an ancillary ligand to generate electron-deficient group 4 metal alkyls; however, the enhanced electrophilicity results in formation of tight ion-pairs in solution.
引用
收藏
页码：3428 / 3430
页数：3
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