Synthesis of Zn2SnO4 octahedron with enhanced H2S gas-sensing performance

被引:24
作者
Xu, Ting-Ting [1 ]
Zhang, Xian-Fa [1 ]
Deng, Zhao-Peng [1 ]
Huo, Li-Hua [1 ]
Gao, Shan [1 ]
机构
[1] Heilongjiang Univ, Sch Chem & Mat Sci, Minist Educ, Key Lab Funct Inorgan Mat Chem, Harbin 150080, Heilongjiang, Peoples R China
基金
中国国家自然科学基金; 对外科技合作项目(国际科技项目);
关键词
Zn2SnO4; Octahedron; Hydrothermal; H2S gas sensor; Selectivity; THIN-FILM; SENSORS; NANOWIRES; MICROSPHERES; ELECTRODES; ZNSNO3; ROUTE;
D O I
10.1016/j.poly.2018.06.016
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Zinc stannate (Zn2SnO4) that used for detecting traces of H2S was less concerned. In this work, Zn2SnO4 octahedra with the average size of 0.18 mu m were prepared through a facile hydrothermal method followed by an annealing process in air atmosphere. The fabricated sensor shows excellent selectivity and sensitivity to H2S at working temperature of 170 degrees C. The gas response exhibits good linear relationship with the increasing of concentrations in the range of 5-10 ppm. The response to 100 ppm H2S can reach up to 172.5 and the lowest detection limit is down to 5 ppb. Such outstanding gas property might be attributed to the morphology of the octahedra and the increased contact area between Zn(2)Sna(4) and target gas, which may has potential applications in detecting traces of H2S. (C) 2018 Elsevier Ltd. All rights reserved.
引用
收藏
页码:510 / 514
页数:5
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