Lanthanide coordination polymers with 1,2-phenylenediacetate

被引：5

作者：

Badiane, Insa ^{[1
,2
]}

Freslon, Stephane ^{[1
]}

Suffren, Yan ^{[1
]}

Daiguebonne, Carole ^{[1
]}

Calvez, Guillaume ^{[1
]}

Bernot, Kevin ^{[1
]}

Camara, Magatte ^{[2
]}

Guillou, Olivier ^{[1
]}

机构：

[1] INSA Rennes, UMR 6226, Inst Sci Chim Rennes, F-35708 Rennes, France

[2] Univ Assane Seck Ziguinchor, LCPM Grp Mat Inorgan Chim Douce & Cristallog, BP 523, Ziguinchor, Senegal

来源：

INORGANICA CHIMICA ACTA | 2017年 / 461卷

关键词：

Lanthanide; Coordination polymer; Crystal structure; Luminescence; Energy transfer; METAL-ORGANIC FRAMEWORKS; CRYSTAL-STRUCTURE; HYDROTHERMAL SYNTHESIS; LUMINESCENCE; COMPLEXES; FAMILY; PROGRAM; DESIGN; LIGAND; ACID;

D O I：

10.1016/j.ica.2017.02.012

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions in water between lanthanide chlorides and the di-sodium salt of 1,2-phenylenediacetic acid, Na-2(o-pda), lead to two families of coordination polymers with respective chemical formulae [La-2(o-pda)(3)(H2O)(4),4H(2)O](infinity) (1) and [Ln(2)(o-pda)(3)(H2O)(2),2H(2)O](infinity) (2) for Ln = Ce-Nd, Sm-Lu and Y. Compound 1 crystallises in the monoclinic system, space group C2/c (n degrees 15), with a = 28.195(5) angstrom, b = 12.2305(3) angstrom, c = 8.7607(1) angstrom, beta = 98.835(1) angstrom and Z = 4. Its crystal structure and thermal properties are described. Compounds of family 2 are isostructural to a previously reported crystal structure. Luminescence properties of Eu-and Tb-based compounds have been studied. (C) 2017 Elsevier B. V. All rights reserved.

引用

页码：136 / 144

页数：9

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