Review: Voltammetric properties and applications of hydrazones and azo moieties

被引：18

作者：

Lawrence, Mark A. W. ^{[1
,2
]}

Lorraine, Shannen C. ^{[1
]}

Wilson, Kerrie-Ann ^{[2
]}

Wilson, Kirk ^{[2
]}

机构：

[1] Univ West Indies Mona, Dept Chem, Kingston 7, Jamaica

[2] Univ Technol, Sch Nat & Appl Sci, 237 Old Hope Rd, Kingston 6, Jamaica

来源：

POLYHEDRON | 2019年 / 173卷

关键词：

Voltammetry; Hydrazones; Azo compounds; Synthesis; Review; DI-2-PYRIDYL KETONE THIOSEMICARBAZONE; MOLECULAR SENSING BEHAVIOR; ELECTROCHEMICAL PROPERTIES; METAL-COMPLEXES; SCHIFF-BASES; SPECTROSCOPIC CHARACTERIZATION; STRUCTURAL-CHARACTERIZATION; CRYSTAL-STRUCTURES; ELECTRON-TRANSFER; PALLADIUM(II) COMPLEXES;

D O I：

10.1016/j.poly.2019.114111

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Hydrazones and azo compounds have been actively studied for more than a century, with thousands of papers presented in the literature. Both functional groups allow for facile structural isomerization, leading to their applications as molecular switches and also as detectors for various environmental stimuli. With each decade, new applications are explored, however the fundamentals of the redox properties drive the ultimate usefulness of both moieties in applications where there is the possibility of a redox reaction occurring. This review highlights the general synthetic routes, some useful applications of hydrazones and azo compounds, as well as their general voltammetric properties under reductive and oxidative conditions, with an emphasis on non-aqueous media. (C) 2019 Elsevier Ltd. All rights reserved.

引用

页数：18

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