Superionic Conductivity of (TlGaSe2)1-x(TlInS2)x Solid Solutions

被引：2

作者：

Sardarli, R. M. ^{[1
]}

Abdullayev, A. P. ^{[1
]}

Aliyeva, N. A. ^{[1
]}

Salmanov, F. T. ^{[1
]}

Yusifov, M. Y. ^{[1
]}

Orudjeva, A. A. ^{[1
]}

机构：

[1] Natl Acad Sci Azerbaijan, Inst Radiat Problems, AZ-1143 Baku, Azerbaijan

来源：

SEMICONDUCTORS | 2018年 / 52卷 / 10期

关键词：

TLGATE2; CRYSTALS;

D O I：

10.1134/S1063782618100184

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

Samples of (TlGaSe2)(1-x)(TlInS2)(x) solid solutions are synthesized. The frequency dependences (2x 10(1)-10(6) Hz) of components of the total complex impedance are studied by the impedance spectroscopy technique and relaxation processes are investigated depending on the composition of the (TlGaSe2)(1-x)(TlInS2)(x) solid solution in the solubility region (x = 0-0.4). Corresponding diagrams on the (Z''-Z') complex plane are analyzed using the equivalent substitutional circuit method. An anomaly in the temperature dependence of the electrical conductivity, which manifests itself in an abrupt increase in the conductivity, is found for the studied (TlGaSe2)(1-x)(TlInS2)(x) solid solution at 400 K. This peculiarity is associated with the phase transition into the superionic state.

引用

页码：1229 / 1232

页数：4

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