Synthesis, characterization and reactivity ratios of poly N-(p-bromophenyl)-2-methacrylamide-Co-N-vinyl-2-pyrrolidone

被引：7

作者：

Thirumoolan, D. ^{[1
]}

Basha, K. Anver ^{[1
]}

Kanai, Tapan ^{[2
]}

Safiullah, S. Mohammed ^{[1
]}

Vetrivel, K. ^{[1
]}

Wasi, K. Abdul ^{[1
]}

Ranjithkumar, B. ^{[1
]}

机构：

[1] C Abdul Hakeem Coll, PG & Res Dept Chem, Melvisharam 632509, Tamil Nadu, India

[2] Naval Mat Res Lab, Div Polymer, Add Ambernath 421506, India

来源：

JOURNAL OF SAUDI CHEMICAL SOCIETY | 2016年 / 20卷 / 02期

关键词：

N-(p-bromophenyl)-2-methacrylamide; N-vinyl-2-pyrrolidone; Monomer reactivity ratios; Thermo gravimetric analysis; GLYCIDYL METHACRYLATE; LINEAR METHODS; CRITICAL REEXAMINATION; METHYL-METHACRYLATE; STYRENE COPOLYMERS; BEHAVIOR; HOMOPOLYMER; ADHESIVES;

D O I：

10.1016/j.jscs.2013.09.003

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The methacrylamide monomer, N-(p-bromophenyl)-2-methacrylamide (PBPMA) was synthesized by reacting p-bromoaniline dissolved in ethylmethylketone (EMK) with methacryloyl chloride in the presence of triethylamine. The copolymers of PBPMA with N-Vinyl-2-pyrrolidone (NVP) were synthesized by free radical solution polymerization using EMK as a solvent at 70 +/- 1 degrees C and benzoyl peroxide as a free radical initiator. The copolymerization behavior was studied in a wide composition interval with the mole fractions of PBPMA ranging from 0.20 to 0.80 in the feed. The copolymers were characterized by FT-IR, H-1 NMR, C-13 NMR and GPC. The solubility was tested in various polar and non polar solvents. The thermogravimetric analysis of the polymers showed that the thermal stability of the copolymer increases with PBPMA content. The copolymer composition was determined by elemental analysis. The monomer reactivity ratios were determined by the application of conventional linearization methods such as Fineman Ross, Kelen-Tudos methods, and a non-linear error-in-variable model (EVM) method using a computer program. (C) 2013 Production and hosting by Elsevier B.V. on behalf of King Saud University.

引用

页码：195 / 200

页数：6

共 26 条

[1] Akelah A., 1990, Functionalized Polymers and their Application
[2] The mechanism of copolymerilzatlon
Alfrey, T
Goldfinger, G
[J]. JOURNAL OF CHEMICAL PHYSICS, 1944, 12 (06) : 205 - 209
[3] Coskun M, 1997, J MACROMOL SCI PURE, VA34, P91
[4] Copolymerization and monomer reactivity ratios of 2-(3-mesityl-3-methylcyclobutyl)-2-hydroxyethyl methacrylate with acrylonitrile
Demirelli, K
Coskun, M
Erol, I
[J]. EUROPEAN POLYMER JOURNAL, 2000, 36 (01) : 83 - 88
[5] A MICROCOMPUTER PROGRAM FOR ESTIMATION OF COPOLYMERIZATION REACTIVITY RATIOS
DUBE, M
SANAYEI, RA
PENLIDIS, A
ODRISCOLL, KF
REILLY, PM
[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1991, 29 (05) : 703 - 708
[6] Free-radical-initiated copolymerization of 2-(2-naphthylamino)-2-oxo-ethyl methacrylate with methyl methacrylate and styrene
Erol, I
Soykan, C
[J]. POLYMER INTERNATIONAL, 2004, 53 (09) : 1235 - 1244
[7] Synthesis and characterization of novel methacrylates derived from morpholine and pyrrolidine:: The determination of kinetic parameters with thermogravimetric analysis
Erol, I
Soykan, C
Türkmen, H
Tufan, Y
[J]. JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY, 2003, A40 (11): : 1213 - 1225
[8] LINEAR METHOD FOR DETERMINING MONOMER REACTIVITY RATIOS IN COPOLYMERIZATION
FINEMAN, M
ROSS, SD
[J]. JOURNAL OF POLYMER SCIENCE, 1950, 5 (02): : 259 - 262
[9] Homopolymer of 4-propanoylphenyl methacrylate and its copolymers with glycidyl methacrylate: synthesis, characterization, reactivity ratios and application as adhesives
Gordon, GGA
Selvamalar, CSJ
Penlidis, A
Nanjundan, S
[J]. REACTIVE & FUNCTIONAL POLYMERS, 2004, 59 (03) : 197 - 209
[10] Lead-ion potentiometric sensor based on electrically conducting microparticles of sulfonic phenylenediamine copolymer
Huang, Mei-Rong
Ding, Yong-Bo
Li, Xin-Gui
[J]. ANALYST, 2013, 138 (13) : 3820 - 3829

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