Synthesis and luminescence properties of CaAl2O4:Mn4+ phosphor

被引：72

作者：

Cao, Renping ^{[1
]}

Zhang, Fenxiang ^{[1
]}

Cao, Chunyan ^{[1
]}

Yu, Xiaoguang ^{[1
]}

Liang, Aihui ^{[2
]}

Guo, Siling ^{[1
]}

Xue, Hongdong ^{[1
]}

机构：

[1] Jinggangshan Univ, Coll Math & Phys, Jian 343009, Jiangxi, Peoples R China

[2] Jiangxi Normal Univ, Coll Chem & Chem Engn, Nanchang 330022, Peoples R China

来源：

OPTICAL MATERIALS | 2014年 / 38卷

基金：

中国国家自然科学基金;

关键词：

Optical materials; Red-emitting; Phosphor; Solid-state reaction method; RED-EMITTING PHOSPHOR; MN4+ IONS; PHOTOLUMINESCENCE; EMISSION; GD; LN;

D O I：

10.1016/j.optmat.2014.10.002

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

CaAl2-yO4:yMn(4+) (y = 0-1.6 mol%) phosphors are synthesized by a solid-state reaction method in air, and their crystal structure and luminescence property are investigated. To compare luminescence property, CaAl3.99O7:1%Mn4+ and SrAl1.99O4:1%Mn4+ phosphors are also synthesized at the same condition. Broad band excitation spectra are observed within the range 220-550 nm, and emission spectra cover from 600 to 720 nm with the strongest emission peak at similar to 658 nm owing to the E-2 -> (4)A(2) transition of Mn4+ ion. The influence of crystal field to luminous intensity is discussed, and the possible luminous mechanism of Mn4+ ion is explained by using energy level diagram of Mn4+ ion. CaAL(1.99)O(4):1%Mn4+, CaAl3.99O7:1%Mn4+, and SrAl1.99O4:1%Mn4+ phosphors under excitation 325 nm light emit red light, and their CIE chromaticity coordinates are (0.7181, 0.2813), (0.7182, 0.2818), and (0.7198, 0.2801), respectively. These contents in the paper are helpful to develop novel and high-efficient Mn4+-doped phosphor for white LEDs. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：53 / 56

页数：4

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