Extraction-chromatographic determination of hydrazine in natural water as a 5,7-dinitrobenzofurazan derivative using diode-array detection

被引：14

作者：

Evgen'ev, MI ^{[1
]}

Evgen'eva, II ^{[1
]}

Ismailova, RN ^{[1
]}

机构：

[1] Kazan State Technol Univ, Kazan 420015, Tatarstan, Russia

来源：

JOURNAL OF ANALYTICAL CHEMISTRY | 2000年 / 55卷 / 10期

关键词：

D O I：

10.1007/BF02756083

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The conditions for the derivatization of hydrazine with p-dimethylaminobenzaldehyde and 4-chloro-5,7-dinitrobenzofurazan, extraction preconcentration of derivatives from natural water, and HPLC determination of the toxicant with diode-array detection were studied. The 5,7-dinitrobenzofurazan derivative was quantitatively extracted from water with isoamyl alcohol and a mixture of isoamyl alcohol with methylene chloride at pH 3-4. A procedure was developed for the extraction-chromatographic determination of hydrazine in water with c(min) = 0.05 mu g/L and the analytical range 0.12-60 mu g/L. The concentration of hydrazine in lake Kaban water was determined.

引用

页码：933 / 937

页数：5

共 17 条

[1]

*AM SOC TEST MAT, ANN BOOK ASTM STA 31, P425

[2] FLUORESCENT DETECTION OF HYDRAZINE, MONOMETHYLHYDRAZINE, AND 1,1-DIMETHYLHYDRAZINE BY DERIVATIZATION WITH AROMATIC DICARBALDEHYDES [J].

COLLINS, GE ;

ROSEPEHRSSON, SL .

ANALYST, 1994, 119 (08) :1907-1913

[3]

Evgen'ev M.I., 1995, ZH ANAL KHIM, V50, P642

[4]

EVGENEV MI, 1993, IZV VUZ KHIM KH TEKH, V36, P40

[5]

EVGENEV MI, 1999, IZV VYSSH UCHEBN ZAV, V42, P51

[6]

EVGENEV MI, 1998, ZH ANAL KHIM, V53, P272

[7]

GADASKINA LD, 1971, PREVRASHCHENIE RASPR, P303

[8]

GREKOV AP, 1979, FIZICHESKAYA KHIMIYA

[9]

GREKOV AR, 1981, GIDRAZINOMETRIYA

[10]

*INT HLTH ORG, 1991, 68 INT HLTH ORG

← 1 2 →