Fumed silica-based organogels and 'aqueous-organic' bigels

被引:75
作者
Patel, A. R. [1 ]
Mankoc, B. [1 ]
Bin Sintang, M. D. [1 ]
Lesaffer, A. [2 ]
Dewettinck, K. [1 ]
机构
[1] Univ Ghent, Fac Biosci Engn, Lab Food Tech & Engn, Vandemoortele Ctr Lipid Sci & Technol, B-9000 Ghent, Belgium
[2] Vandemoortele R&D Izegem, B-8870 Izegem, Belgium
关键词
RHEOLOGICAL PROPERTIES; PARTICLE SUSPENSIONS; POLYMER ADSORPTION; SOLVATION FORCES; DRUG-DELIVERY; OLEOGELS; GELS; MICROSTRUCTURE; BEHAVIOR; GELATION;
D O I
10.1039/c4ra15437a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We report the use of fumed silica (hydrophilic colloidal silica particles) to generate triglyceride solvent-based soft matter systems (organogels and bigels). Interestingly, the bigels showed a better gel strength compared to organogels while showing a comparatively weaker thixotropic recovery. Electron microscopy and energy dispersive X-ray spectroscopy were used to understand the microstructure of these new thixotropic molecular gel systems with respect to the fractal-like aggregation of silica particles as well as the percolating network of organic-aqueous phases.
引用
收藏
页码:9703 / 9708
页数:6
相关论文
共 47 条
[1]  
[Anonymous], 2005, ANGEW CHEM, DOI DOI 10.1002/ANGE.200462470
[2]   Particles as surfactants - similarities and differences [J].
Binks, BP .
CURRENT OPINION IN COLLOID & INTERFACE SCIENCE, 2002, 7 (1-2) :21-41
[3]   Aggregation dynamics, structure, and mechanical properties of bigels [J].
Di Michele, L. ;
Fiocco, D. ;
Varrato, F. ;
Sastry, S. ;
Eiser, E. ;
Foffi, G. .
SOFT MATTER, 2014, 10 (20) :3633-3648
[4]   AMORPHOUS SYNTHETIC SILICA PRODUCTS IN POWDER FORM .2. APPLICATIONS [J].
FERCH, H .
PROGRESS IN ORGANIC COATINGS, 1982, 10 (01) :91-118
[5]   Morphology and surface properties of fumed silicas [J].
Gun'ko, VM ;
Mironyuk, IF ;
Zarko, VI ;
Voronin, EF ;
Turov, VV ;
Pakhlov, EM ;
Goncharuk, EV ;
Nychiporuk, YM ;
Vlasova, NN ;
Gorbik, PP ;
Mishchuk, OA ;
Mishchuk, OA ;
Chuiko, AA ;
Kulik, TV ;
Palyanytsya, BB ;
Pakhovchishin, SV ;
Skubiszewska-Zieba, J ;
Janusz, W ;
Turov, AV ;
Leboda, R .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2005, 289 (02) :427-445
[6]   Fumed silicas possessing different morphology and hydrophilicity [J].
Gun'ko, VM ;
Mironyuk, IF ;
Zarko, VI ;
Turov, VV ;
Voronin, EF ;
Pakhlov, EM ;
Goncharuk, EV ;
Leboda, R ;
Skubiszewska-Zieba, J ;
Janusz, W ;
Chibowski, S ;
Levchuk, YN ;
Klyueva, AV .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2001, 242 (01) :90-103
[7]   Analytical and related applications of organogels [J].
Hinze, WL ;
Uemasu, I ;
Dai, F ;
Braun, JM .
CURRENT OPINION IN COLLOID & INTERFACE SCIENCE, 1996, 1 (04) :502-513
[8]   Potential food applications of edible oil organogels [J].
Hughes, Naomi E. ;
Marangoni, Alejandro G. ;
Wright, Amanda J. ;
Rogers, Michael A. ;
Rush, James W. E. .
TRENDS IN FOOD SCIENCE & TECHNOLOGY, 2009, 20 (10) :470-480
[9]   Rheological properties of thermoplastic polyurethane adhesive solutions containing fumed silicas of different surface areas [J].
Jaúregui-Beloqui, B ;
Fernández-García, JC ;
Orgilés-Barceló, AC ;
Mahiques-Bujanda, MM ;
Martín-Martínez, JM .
INTERNATIONAL JOURNAL OF ADHESION AND ADHESIVES, 1999, 19 (04) :321-328
[10]   RHEOLOGICAL PROPERTIES OF SILICA SUSPENSIONS IN POLYMER-SOLUTIONS [J].
KAWAGUCHI, M .
ADVANCES IN COLLOID AND INTERFACE SCIENCE, 1994, 53 :103-127