Development of the Applications of Palladium on Charcoal in Organic Synthesis

被引：99

作者：

Liu, Xiang ^{[1
]}

Astruc, Didier ^{[2
]}

机构：

[1] China Three Gorges Univ, Key Lab Inorgan Nonmetall Crystalline & Energy Co, Coll Mat & Chem Engn, Yichang 443002, Hubei, Peoples R China

[2] Univ Bordeaux, CNRS, UMR 5255, ISM, 351 Cours Liberat, F-33405 Talence, France

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2018年 / 360卷 / 18期

关键词：

catalysis; colloids; green chemistry; heterogeneous catalysis; organic synthesis; palladium on charcoal (Pd/C); CROSS-COUPLING REACTIONS; CATALYZED LIGAND-FREE; D EXCHANGE-REACTION; BAYLIS-HILLMAN REACTION; HECK-TYPE REACTION; ADHESION MOLECULE-1 INTERACTION; FORMING REDUCTIVE ELIMINATION; EXCITED-STATE PHOTODYNAMICS; ELECTRON-WITHDRAWING GROUPS; WATER-SOLUBLE PHOSPHINES;

D O I：

10.1002/adsc.201800343

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Palladium on charcoal (Pd/C) has lots of salient merits: (i) it is a cheap and commercial source of palladium, (ii) it shows efficient catalytic activity even without ligands, (iii) as a heterogeneous catalyst it is easily recycled many times by simple filtration, and (iv) it is applicable to a great number of reactions and substrates, although it is eventually less efficient than homogeneous Pd catalysts containing some sophisticated ligands. This review recalls the main background and summarizes the progress made essentially during the last twelve years in Pd/C-catalyzed organic synthesis since the reviews by Felpin Q s group and Seki in 2006. 1 Introduction 2 Properties of Pd/C 3 Applications of Pd/C 3.1 Dehydrogenation 3.2 Michael Addition 3.3 C-C Coupling 3.3.8 Homo-Coupling 3.4 C-N Coupling 3.5 C-S Coupling 3.6 C-P Coupling 3.7 Si-O Coupling 3.8 C-O Coupling 3.9 Carbonylation 3.10 Polymerization 3.11 Oxidation 3.12 Hydrogenolysis 3.13 Hydrogenation 3.14 Cyclization 4 Conclusion and Outlook

引用

页码：3426 / 3459

页数：34

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