Electrochemistry and MO Computations of Saturated and Unsaturated N-Heterocyclic Silylenes

被引：5

作者：

Zark, Patrick ^{[1
]}

Mueller, Thomas ^{[1
]}

West, Robert ^{[2
]}

Pravinkumar, Kendrekar ^{[3
]}

Becker, James Y. ^{[3
]}

机构：

[1] Carl von Ossietzky Univ Oldenburg, Inst Reine & Angew Chem, D-26129 Oldenburg, Germany

[2] Univ Wisconsin, Dept Chem, Organosilicon Res Ctr, Madison, WI 53706 USA

[3] Ben Gurion Univ Negev, Dept Chem, IL-84105 Beer Sheva, Israel

来源：

ORGANOMETALLICS | 2010年 / 29卷 / 07期

基金：

以色列科学基金会;

关键词：

STABLE SILYLENE; REACTIVITY;

D O I：

10.1021/om901037j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The results of electrochemical investigations by cyclic voltammetry and density functional computations of new saturated (2, 3) and unsaturated N-heterocyclic silylenes (5, 6) are described and compared with the previously known N-heterocyclic silylenes (1, 4). Good correlations have been found between experimental oxidation potentials of saturated 1-3 and unsaturated 4-6 with those of density functional calculations of the electronic properties of these divalent silicon derivatives.

引用

页码：1603 / 1606

页数：4

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