Visible Light Induced Metal-Free Carbene N-Carbazolation

被引：66

作者：

Empel, Claire ^{[1
]}

Patureau, Frederic W. ^{[1
]}

Koenigs, Rene M. ^{[1
]}

机构：

[1] Rhein Westfal TH Aachen, Inst Organ Chem, Landoltweg 1, D-52074 Aachen, Germany

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2019年 / 84卷 / 17期

基金：

欧洲研究理事会;

关键词：

KIRMSE REARRANGEMENT REACTIONS; HETEROARENE CARBOXYLIC-ACIDS; AMINATION; INSERTION; FUNCTIONALIZATION; PHOTOLYSIS; ARYLATION; PHENOLS; SERIES; GREEN;

D O I：

10.1021/acs.joc.9b01753

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Metal-free N-H functionalization reactions represent an important strategy for sustainable C-N coupling reactions. In this report, we describe the visible light photolysis of aryl diazoacetates in the presence of some N-heterocycles that enables mild, metal-free N-H functionalization reactions of carbazole and azepine heterocycles (15 examples, up to 83% yield).

引用

页码：11316 / 11322

页数：7

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