Synthesis and characterisation of trisarylphosphine selenides: Further insight into the effect of fluoroalkylation on the electronic properties of trisarylphosphines

被引：16

作者：

Adams, Dave J. ^{[1
]}

Bennett, James A. ^{[1
]}

Duncan, Daniel ^{[1
]}

Hope, Eric G. ^{[1
]}

Hopewell, Jonathan ^{[1
]}

Stuart, Alison M. ^{[1
]}

West, Andrew J. ^{[1
]}

机构：

[1] Univ Leicester, Dept Chem, Leicester LE1 7RH, Leics, England

来源：

POLYHEDRON | 2007年 / 26卷 / 07期

基金：

英国工程与自然科学研究理事会;

关键词：

phosphine; fluorous; NMR; selenide;

D O I：

10.1016/j.poly.2006.11.025

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Variations in the magnitude of the lis, coupling constants for a range of phosphorus(V) selenides allow the efficiency of different spacer groups at insulating the phosphorus centre in triarylphosphines from highly electron-withdrawing perfluoroalkyl groups to be established. (C) 2006 Elsevier Ltd. All rights reserved.

引用

页码：1505 / 1513

页数：9

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