Ultrasonic Study of Molecular Interactions in Binary Mixtures at 303 K

被引：10

作者：

Mullainathan, S. ^{[1
]}

Nithiyanantham, S. ^{[2
]}

机构：

[1] Coll Engn, AVC, Dept Phys, Mayiladuthurai 609305, Tamil Nadu, India

[2] SRM Univ, Dept Phys, Ultrason Div, Kattankulathur 603203, Tamil Nadu, India

来源：

E-JOURNAL OF CHEMISTRY | 2010年 / 7卷 / 02期

关键词：

Ultrasonic velocity; Acoustical properties; Molecular interactions;

D O I：

10.1155/2010/264929

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The ultrasonic velocity, density and viscosity at 303 K have been measured in the binary systems of 1,4-dioxane and acetone with water. From the experimental data, various acoustical parameters such as adiabatic compressibility (beta), intermolecular free length (L-f), free volume (V-f), internal pressure (pi(i)), Rao's constant (R), Wada's constant (W) and specific acoustical impedance (Z) were calculated. The results are interpreted in terms of molecular interaction between the components of the mixtures.

引用

页码：353 / 356

页数：4

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