Novel light-emitting polymers containing donor and acceptor architectures

被引：18

作者：

Chen, Y ^{[1
]}

Sheu, RB ^{[1
]}

Wu, TY ^{[1
]}

机构：

[1] Natl Cheng Kung Univ, Dept Chem Engn, Tainan 701, Taiwan

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2003年 / 41卷 / 06期

关键词：

iminodibenzyl; distyrylbenzene; oxadiazole; conjugated polymers; UV-vis spectroscopy; excimer; luminescence; electrochemical property; light-emitting diodes (LED);

D O I：

10.1002/pola.10621

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

It is desirable to design and synthesize a bipolar polymer that possesses both a hole-injecting/transporting segment and an electron-affinitive segment to balance the rates of injection of electrons and holes, and to enhance the charge-injecting/transporting ability. As such, the synthesis and primary characterization of four novel alternating copolymers containing π-deficient and π-excessive units in a conjugated main chain for pursuing efficient single-layer polymer light-emitting diodes (LEDs) are presented. It is found that the resulting copolymers are thermally stable above 370°C.

引用

页码：725 / 731

页数：7

共 29 条

[1] POLY(P-PHENYLENEVINYLENE) LIGHT-EMITTING-DIODES - ENHANCED ELECTROLUMINESCENT EFFICIENCY THROUGH CHARGE CARRIER CONFINEMENT [J].

BROWN, AR ;

BRADLEY, DDC ;

BURROUGHES, JH ;

FRIEND, RH ;

GREENHAM, NC ;

BURN, PL ;

HOLMES, AB ;

KRAFT, A .

APPLIED PHYSICS LETTERS, 1992, 61 (23) :2793-2795

[2] Aggregated states of luminescent conjugated polymers in solutions [J].

Chang, R ;

Hsu, JH ;

Fann, WS ;

Yu, J ;

Lin, SH ;

Lee, YZ ;

Chen, SA .

CHEMICAL PHYSICS LETTERS, 2000, 317 (1-2) :153-158

[3] Synthesis and characterization of luminescent polyethers with 2,5-distyrylthiophene and aromatic oxadiazole chromophores [J].

Chen, Y ;

Huang, YY ;

Wu, TY .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2002, 40 (17) :2927-2936

[4] REALIZATION OF A BLUE-LIGHT-EMITTING DEVICE USING POLY(PARA-PHENYLENE) [J].

GREM, G ;

LEDITZKY, G ;

ULLRICH, B ;

LEISING, G .

ADVANCED MATERIALS, 1992, 4 (01) :36-37

[5]

GREM G, 1992, SYNTHETIC MET, V51, P389

[6] Synthesis, optical, and electrochemical properties of novel copolymers on the basis of benzothiadiazole and electron-rich arene units [J].

Jayakannan, M ;

Van Hal, PA ;

Janssen, RAJ .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2002, 40 (14) :2360-2372

[7] Synthesis and structure-property relationship of new donor-acceptor-type conjugated monomers and polymers on the basis of thiophene and benzothiadiazole [J].

Jayakannan, M ;

Van Hal, PA ;

Janssen, RAJ .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2002, 40 (02) :251-261

[8] HIGHLY-CONDUCTING, POLY(2,5-THIENYLENE VINYLENE) PREPARED VIA A SOLUBLE PRECURSOR POLYMER [J].

JEN, KY ;

MAXFIELD, M ;

SHACKLETTE, LW ;

ELSENBAUMER, RL .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (04) :309-311

[9] New conjugated polymers with donor-acceptor architectures: Synthesis and photophysics of carbazole-quinoline and phenothiazine-quinoline copolymers and oligomers exhibiting large intramolecular charge transfer [J].

Jenekhe, SA ;

Lu, LD ;

Alam, MM .

MACROMOLECULES, 2001, 34 (21) :7315-7324

[10] A convenient synthetic route to poly(p-phenylene-1,2-diphenylvinylenes) [J].

Johansson, DM ;

Theander, M ;

Inganäs, O ;

Andersson, MR .

SYNTHETIC METALS, 2000, 113 (03) :293-297

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