Enhanced fluorescence properties of terbium complex/poly-L-lactic acid superfine fibers sensitized by the LSPR effect of silver nanoparticles

被引：3
作者：
Wen, Shipeng [1 ]
Zhang, Guiming [1 ]
Zhang, Rong [1 ]
Zhang, Liqun [1 ]
Liu, Li [1 ,2 ]
机构：
[1] Beijing Univ Chem Technol, Beijing Engn Res Ctr Adv Elastomers, Beijing 100029, Peoples R China
[2] Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China
来源：
RSC ADVANCES | 2017年 / 7卷 / 32期
基金：
中国国家自然科学基金;
关键词：
SURFACE-PLASMON RESONANCE; LIGHT-EMITTING DEVICES; ELECTROSPINNING PREPARATION; COMPOSITE NANOFIBERS; LUMINESCENCE; PARTICLES; GLASSES; FILMS; GOLD;
D O I：
10.1039/c7ra02401k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In this research, Ag-NPs/Tb-complex/PLLA composite fibers with diameters of around 250 nm were successfully obtained by the electrospinning and characterized by scanning electron microscope (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS) and fluorescence spectra. The influence of localized surface plasmon resonance (LSPR) of silver nanoparticles (Ag-NPs) on the fluorescence of Tb(acac)(3)phen/poly-L-lactic acid (Tb-complex, acac = acetylacetone; phen = phenanthroline, PLLA = poly-L-lactic acid) fibers was mainly investigated. It is found that Tb-complex dispersed in the fibers in the form of nanoclusters. The local field surrounding of Tb3+ ions was affected by the neighboring Ag-NPs. As a result of the LSPR effect of Ag-NPs, the fluorescence intensity, quantum efficiency of Tb-complex in the composite fibers with the Ag/Tb ratio of 4 : 1, were simultaneously improved compared with the composite fibers without Ag-NPs.
引用
收藏
页码：19808 / 19814
页数：7
相关论文
共 35 条
  • [1] Plasmonic optical sensors printed from Ag-PVA nanoinks
    Abargues, Rafael
    Rodriguez-Canto, Pedro J.
    Albert, Sandra
    Suarez, Isaac
    Martinez-Pastor, Juan P.
    [J]. JOURNAL OF MATERIALS CHEMISTRY C, 2014, 2 (05) : 908 - 915
  • [2] Fluorescence Enhancement at Docking Sites of DNA-Directed Self-Assembled Nanoantennas
    Acuna, G. P.
    Moeller, F. M.
    Holzmeister, P.
    Beater, S.
    Lalkens, B.
    Tinnefeld, P.
    [J]. SCIENCE, 2012, 338 (6106) : 506 - 510
  • [3] Biosensing with plasmonic nanosensors
    Anker, Jeffrey N.
    Hall, W. Paige
    Lyandres, Olga
    Shah, Nilam C.
    Zhao, Jing
    Van Duyne, Richard P.
    [J]. NATURE MATERIALS, 2008, 7 (06) : 442 - 453
  • [4] A simple and effective route for the preparation of poly(vinylalcohol) (PVA) nanofibers containing gold nanoparticles by electrospinning method
    Bai, Jie
    Li, Yaoxian
    Yang, Songtao
    Du, Jianshi
    Wang, Shugang
    Zheng, Jifu
    Wang, Yongzhi
    Yang, Qingbiao
    Chen, Xuesi
    Jing, Xiabin
    [J]. SOLID STATE COMMUNICATIONS, 2007, 141 (05) : 292 - 295
  • [5] Fluorescence Quenchers in Mixed Phase Polyfluorene Films
    Bansal, Ashu K.
    Ruseckas, Arvydas
    Shaw, Paul E.
    Samuel, Ifor D. W.
    [J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (41) : 17864 - 17867
  • [6] Bohren C. F., 1983, WILEY INTERSCIENCE, V98, P290
  • [7] Theory of surface-plasmon resonance optical-field enhancement at prolate spheroids
    Calander, N
    Willander, M
    [J]. JOURNAL OF APPLIED PHYSICS, 2002, 92 (09) : 4878 - 4884
  • [8] Electrically conductive nanofibers with highly oriented structures and their potential application in skeletal muscle tissue engineering
    Chen, Mei-Chin
    Sun, Yu-Chin
    Chen, Yuan-Hsiang
    [J]. ACTA BIOMATERIALIA, 2013, 9 (03) : 5562 - 5572
  • [9] Plasmonic Enhancement or Energy Transfer? On the Luminescence of Gold-, Silver-, and Lanthanide-Doped Silicate Glasses and Its Potential for Light-Emitting Devices
    Eichelbaum, Maik
    Rademann, Klaus
    [J]. ADVANCED FUNCTIONAL MATERIALS, 2009, 19 (13) : 2045 - 2052
  • [10] Electrospun Fe3O4/PVP//Tb(BA)3phen/PVP magnetic-photoluminescent bifunctional bistrand aligned composite nanofibers bundles
    Gai, Guangqing
    Wang, Liyan
    Dong, Xiangting
    Xu, Shuzhi
    [J]. JOURNAL OF MATERIALS SCIENCE, 2013, 48 (15) : 5140 - 5147
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