Liquid organic hydrogen carriers for transportation and storing of renewable energy - Review and discussion

被引：341
作者：
Aaldto-Saksa, Paivi T. [1 ,2 ]
Cook, Chris [3 ]
Kiviaho, Jari [2 ]
Repo, Timo [1 ]
机构：
[1] Univ Helsinki, POB 55, FI-00014 Helsinki, Finland
[2] VTT Tech Res Ctr Finland Ltd, POB 1000, FI-02044 Espoo, Finland
[3] Univ York, York, N Yorkshire, England
来源：
JOURNAL OF POWER SOURCES | 2018年 / 396卷
关键词：
Hydrogen; Liquid organic hydrogen carriers; Energy storage; Dibenzyl toluene; Methanol; DODECAHYDRO-N-ETHYLCARBAZOLE; CATALYTIC DEHYDROGENATION; MILD HYDROGENATION; ACCEPTORLESS DEHYDROGENATION; TECHNOECONOMIC ANALYSIS; SUPPORTED RUTHENIUM; PHASE HYDROGENATION; STORAGE MATERIALS; H-2; RELEASE; SYSTEM;
D O I：
10.1016/j.jpowsour.2018.04.011
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Transition to renewable energy systems is essential to achieve the climate change mitigation targets. However, the timing and the regions of the production and consumption of the renewable energy do not always match, and different energy storage technologies are needed to secure the uninterrupted energy supply. Liquid organic hydrogen carriers (LOHCs) offer a flexible media for the storage and transportation of renewable energy. These "liquid hydrogen batteries" are reversibly hydrogenated and dehydrogenated using catalysts at elevated temperatures. Commercial LOHC concepts are already available. Another flexible route to store energy is through "circular" hydrogen carriers, such as methanol and methane produced from atmospheric carbon dioxide (CO2). These fuels have a long history as fossil fuels. In this review, the chemistry and state-of-the-art of LOHCs are explored and discussed against defined criteria with comparison made to existing energy storage systems. The LOHCs and "circular" hydrogen carriers were found to be particularly promising hydrogen storage systems.
引用
收藏
页码：803 / 823
页数：21
相关论文
共 167 条
  • [61] Jensen C. M., 2000, U.S. Patent, Patent No. 6074447
  • [62] Current situation and prospect of hydrogen storage technology with new organic liquid
    Jiang, Zhao
    Pan, Qi
    Xu, Jie
    Fang, Tao
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2014, 39 (30) : 17442 - 17451
  • [63] Hydrogen storage using a hot pressure swing reactor
    Jorschick, H.
    Preuster, P.
    Duerr, S.
    Seidel, A.
    Mueller, K.
    Boesmann, A.
    Wasserscheid, P.
    [J]. ENERGY & ENVIRONMENTAL SCIENCE, 2017, 10 (07) : 1652 - 1659
  • [64] Efficient evolution of hydrogen from liquid cycloalkanes over Pt-containing catalysts supported on active carbons under "wet-dry multiphase conditions"
    Kariya, N
    Fukuoka, A
    Ichikawa, M
    [J]. APPLIED CATALYSIS A-GENERAL, 2002, 233 (1-2) : 91 - 102
  • [65] Hydrogenation of naphthalene over NiO/SiO2-Al2O3 catalysts:: Structure-activity correlation
    Kirumakki, Sharath R.
    Shpeizer, Boris G.
    Sagar, Guggilla Vidya
    Chary, Komandur V. R.
    Clearfield, Abraham
    [J]. JOURNAL OF CATALYSIS, 2006, 242 (02) : 319 - 331
  • [66] Ammonia for hydrogen storage: challenges and opportunities
    Klerke, Asbjorn
    Christensen, Claus Hviid
    Norskov, Jens K.
    Vegge, Tejs
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2008, 18 (20) : 2304 - 2310
  • [67] Conversion of CO2 from Air into Methanol Using a Polyamine and a Homogeneous Ruthenium Catalyst
    Kothandaraman, Jotheeswari
    Goeppert, Alain
    Czaun, Miklos
    Olah, George A.
    Prakash, G. K. Surya
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138 (03) : 778 - 781
  • [68] Coupling of a Liquid Organic Hydrogen Carrier System with Industrial Heat
    Krieger, Christoph
    Mueller, Karsten
    Arlt, Wolfgang
    [J]. CHEMICAL ENGINEERING & TECHNOLOGY, 2016, 39 (08) : 1570 - 1574
  • [69] Thermodynamic analysis of reversible hydrogenation for heat storage in concentrated solar power plants
    Krieger, Christoph
    Mueller, Karsten
    Arlt, Wolfgang
    [J]. SOLAR ENERGY, 2016, 123 : 40 - 50
  • [70] Kunze K., 2012, CRYO COMPRESSED HYDR
234567891011