Liquid organic hydrogen carriers for transportation and storing of renewable energy - Review and discussion

被引：366

作者：

Aaldto-Saksa, Paivi T. ^{[1
,2
]}

Cook, Chris ^{[3
]}

Kiviaho, Jari ^{[2
]}

Repo, Timo ^{[1
]}

机构：

[1] Univ Helsinki, POB 55, FI-00014 Helsinki, Finland

[2] VTT Tech Res Ctr Finland Ltd, POB 1000, FI-02044 Espoo, Finland

[3] Univ York, York, N Yorkshire, England

来源：

JOURNAL OF POWER SOURCES | 2018年 / 396卷

关键词：

Hydrogen; Liquid organic hydrogen carriers; Energy storage; Dibenzyl toluene; Methanol; DODECAHYDRO-N-ETHYLCARBAZOLE; CATALYTIC DEHYDROGENATION; MILD HYDROGENATION; ACCEPTORLESS DEHYDROGENATION; TECHNOECONOMIC ANALYSIS; SUPPORTED RUTHENIUM; PHASE HYDROGENATION; STORAGE MATERIALS; H-2; RELEASE; SYSTEM;

D O I：

10.1016/j.jpowsour.2018.04.011

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Transition to renewable energy systems is essential to achieve the climate change mitigation targets. However, the timing and the regions of the production and consumption of the renewable energy do not always match, and different energy storage technologies are needed to secure the uninterrupted energy supply. Liquid organic hydrogen carriers (LOHCs) offer a flexible media for the storage and transportation of renewable energy. These "liquid hydrogen batteries" are reversibly hydrogenated and dehydrogenated using catalysts at elevated temperatures. Commercial LOHC concepts are already available. Another flexible route to store energy is through "circular" hydrogen carriers, such as methanol and methane produced from atmospheric carbon dioxide (CO2). These fuels have a long history as fossil fuels. In this review, the chemistry and state-of-the-art of LOHCs are explored and discussed against defined criteria with comparison made to existing energy storage systems. The LOHCs and "circular" hydrogen carriers were found to be particularly promising hydrogen storage systems.

引用

页码：803 / 823

页数：21

共 167 条

[21] An overview of organic liquid phase hydrogen carriers [J].

Bourane, Abdennour ;

Elanany, Mohamed ;

Pham, Thang V. ;

Katikaneni, Sai P. .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2016, 41 (48) :23075-23091

[22] Dehydrogenation of pyrrolidine based liquid organic hydrogen carriers by an iridium pincer catalyst, an isothermal kinetic study [J].

Brayton, Daniel F. ;

Jensen, Craig M. .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2015, 40 (46) :16266-16270

[23] Evaluation of Industrially Applied Heat-Transfer Fluids as Liquid Organic Hydrogen Carrier Systems [J].

Brueckner, Nicole ;

Obesser, Katharina ;

Boesmann, Andreas ;

Teichmann, Daniel ;

Arlt, Wolfgang ;

Dungs, Jennifer ;

Wasserscheid, Peter .

CHEMSUSCHEM, 2014, 7 (01) :229-235

[24] Mild hydrogenation of quinoline 1. Role of reaction parameters [J].

Campanati, M ;

Vaccari, A ;

Piccolo, O .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2002, 179 (1-2) :287-292

[25] Mild hydrogenation of quinoline - 2. A novel Rh-containing pillared layered clay catalyst [J].

Campanati, M ;

Casagrande, M ;

Fagiolino, I ;

Lenarda, M ;

Storaro, L ;

Battagliarin, M ;

Vaccari, A .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2002, 184 (1-2) :267-272

[26]

Cazzola P., 2013, Production Costs of Alternative Transportation Fuels

[27] A Molecular Iron Catalyst for the Acceptorless Dehydrogenation and Hydrogenation of N-Heterocycles [J].

Chakraborty, Sumit ;

Brennessel, William W. ;

Jones, William D. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (24) :8564-8567

[28] Selective Catalytic Hydrogenation of Heteroarenes with N-Graphene-Modified Cobalt Nanoparticles (Co3O4 Co/NGr@α-Al2O3) [J].

Chen, Feng ;

Surkus, Annette-Enrica ;

He, Lin ;

Pohl, Marga-Martina ;

Radnik, Jorg ;

Topf, Christoph ;

Junge, Kathrin ;

Beller, Matthias .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (36) :11718-11724

[29]

Chernichenko K, 2013, NAT CHEM, V5, P718, DOI [10.1038/NCHEM.1693, 10.1038/nchem.1693]

[30] Thermodynamic efficiencies of hydrogen storage processes using carbazole-based compounds [J].

Choi, In Young ;

Shin, Byeong Soo ;

Kwak, Sang Kyu ;

Kang, Kyung Soo ;

Yoon, Chang Won ;

Kang, Jeong Won .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2016, 41 (22) :9367-9373

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