Liquid organic hydrogen carriers for transportation and storing of renewable energy - Review and discussion

被引：341
作者：
Aaldto-Saksa, Paivi T. [1 ,2 ]
Cook, Chris [3 ]
Kiviaho, Jari [2 ]
Repo, Timo [1 ]
机构：
[1] Univ Helsinki, POB 55, FI-00014 Helsinki, Finland
[2] VTT Tech Res Ctr Finland Ltd, POB 1000, FI-02044 Espoo, Finland
[3] Univ York, York, N Yorkshire, England
来源：
JOURNAL OF POWER SOURCES | 2018年 / 396卷
关键词：
Hydrogen; Liquid organic hydrogen carriers; Energy storage; Dibenzyl toluene; Methanol; DODECAHYDRO-N-ETHYLCARBAZOLE; CATALYTIC DEHYDROGENATION; MILD HYDROGENATION; ACCEPTORLESS DEHYDROGENATION; TECHNOECONOMIC ANALYSIS; SUPPORTED RUTHENIUM; PHASE HYDROGENATION; STORAGE MATERIALS; H-2; RELEASE; SYSTEM;
D O I：
10.1016/j.jpowsour.2018.04.011
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Transition to renewable energy systems is essential to achieve the climate change mitigation targets. However, the timing and the regions of the production and consumption of the renewable energy do not always match, and different energy storage technologies are needed to secure the uninterrupted energy supply. Liquid organic hydrogen carriers (LOHCs) offer a flexible media for the storage and transportation of renewable energy. These "liquid hydrogen batteries" are reversibly hydrogenated and dehydrogenated using catalysts at elevated temperatures. Commercial LOHC concepts are already available. Another flexible route to store energy is through "circular" hydrogen carriers, such as methanol and methane produced from atmospheric carbon dioxide (CO2). These fuels have a long history as fossil fuels. In this review, the chemistry and state-of-the-art of LOHCs are explored and discussed against defined criteria with comparison made to existing energy storage systems. The LOHCs and "circular" hydrogen carriers were found to be particularly promising hydrogen storage systems.
引用
收藏
页码：803 / 823
页数：21
相关论文
共 167 条
  • [21] An overview of organic liquid phase hydrogen carriers
    Bourane, Abdennour
    Elanany, Mohamed
    Pham, Thang V.
    Katikaneni, Sai P.
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2016, 41 (48) : 23075 - 23091
  • [22] Dehydrogenation of pyrrolidine based liquid organic hydrogen carriers by an iridium pincer catalyst, an isothermal kinetic study
    Brayton, Daniel F.
    Jensen, Craig M.
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2015, 40 (46) : 16266 - 16270
  • [23] Evaluation of Industrially Applied Heat-Transfer Fluids as Liquid Organic Hydrogen Carrier Systems
    Brueckner, Nicole
    Obesser, Katharina
    Boesmann, Andreas
    Teichmann, Daniel
    Arlt, Wolfgang
    Dungs, Jennifer
    Wasserscheid, Peter
    [J]. CHEMSUSCHEM, 2014, 7 (01) : 229 - 235
  • [24] Mild hydrogenation of quinoline 1. Role of reaction parameters
    Campanati, M
    Vaccari, A
    Piccolo, O
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2002, 179 (1-2) : 287 - 292
  • [25] Mild hydrogenation of quinoline - 2. A novel Rh-containing pillared layered clay catalyst
    Campanati, M
    Casagrande, M
    Fagiolino, I
    Lenarda, M
    Storaro, L
    Battagliarin, M
    Vaccari, A
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2002, 184 (1-2) : 267 - 272
  • [26] Cazzola P., 2013, Production Costs of Alternative Transportation Fuels
  • [27] A Molecular Iron Catalyst for the Acceptorless Dehydrogenation and Hydrogenation of N-Heterocycles
    Chakraborty, Sumit
    Brennessel, William W.
    Jones, William D.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (24) : 8564 - 8567
  • [28] Selective Catalytic Hydrogenation of Heteroarenes with N-Graphene-Modified Cobalt Nanoparticles (Co3O4 Co/NGr@α-Al2O3)
    Chen, Feng
    Surkus, Annette-Enrica
    He, Lin
    Pohl, Marga-Martina
    Radnik, Jorg
    Topf, Christoph
    Junge, Kathrin
    Beller, Matthias
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (36) : 11718 - 11724
  • [29] Chernichenko K, 2013, NAT CHEM, V5, P718, DOI [10.1038/NCHEM.1693, 10.1038/nchem.1693]
  • [30] Thermodynamic efficiencies of hydrogen storage processes using carbazole-based compounds
    Choi, In Young
    Shin, Byeong Soo
    Kwak, Sang Kyu
    Kang, Kyung Soo
    Yoon, Chang Won
    Kang, Jeong Won
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2016, 41 (22) : 9367 - 9373
12345678910