Coordination Polymers Based on Amphiphilic Oligomeric Silsesquioxanes and Transition Metal Ions (Co2+, Ni2+): Structure and Stimuli-Responsive Properties

被引:1
作者
Shevchenko, Valery [1 ]
Bliznyuk, Valery [2 ]
Gumenna, Mariana [1 ]
Klimenko, Nina [1 ]
Stryutsky, Alexandr [1 ]
Wang, Junlei [3 ]
Binek, Christian [3 ]
Chernyakova, Margarita [4 ]
Belikov, Konstantin [4 ,5 ]
机构
[1] Natl Acad Sci Ukraine, Inst Macromol Chem, Dept Chem Oligomers & Netted Polymers, 48 Kharkivske Shose, UA-02160 Kiev, Ukraine
[2] Clemson Univ, Dept Mat Sci & Engn, 161 Sirrine Hall,515 Calhoun Dr, Clemson, SC 29634 USA
[3] Univ Nebraska, Dept Phys & Astron, 208 Theodore Jorgensen Hall,855 N 16th St, Lincoln, NE 68588 USA
[4] NAS Ukraine, Inst Single Crystals, State Sci Inst, 60 Nauky Ave, UA-61072 Kharkiv, Ukraine
[5] Kharkov Natl Univ, 4 Svobody Sq, UA-61022 Kharkiv, Ukraine
基金
美国国家科学基金会;
关键词
amphiphilic oligomeric silsesquioxanes; complexation; magnetic properties; stimuli‐ responsive properties;
D O I
10.1002/mame.202100085
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Synthesis, structural organization, thermal, and magnetic properties of coordination polymers (OSS-polymer-Me) based on amphiphilic oligomeric silsesquioxanes (OSS) and transition metal ions (Co2+, Ni2+) are reported. The initial amphiphilic OSS containing various ratios of n-octadecylurethane and carboxyl groups (OSS-C18H37-x-COOH-y) are characterized with two types of ordered phases. The first one is a supramolecular structure stabilized by hydrogen bonds and characterized with a specific endothermic transition on differential scanning calorimetry thermograms (T-m1). The second one is presented by crystalline domains of aliphatic chains with a melting transition peak (T-m2). Inclusion of metals has no effect on the magnitude of T-m2 while leading to a decrease in the value of the T-m1 in comparison to the same compounds without metal. Being located in the nodes of the irregular network structure of OSS-polymer-Me, metal ions form approximate to 2 nm clusters, which connect multifunctional molecules of OSS-C18H37-x-COOH-y in a supramolecular system similar to disordered metal-organic framework. The OSS-polymer-Me nanocomposites display superparamagnetic properties determined by an adaptive behavior of the intermolecular network. The latter can be modified by the application of an external magnetic field and/or moderate heat.
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页数:15
相关论文
共 71 条
[21]   Mesostructured Nanomagnetic Polyhedral Oligomeric Silsesquioxanes (POSS) Incorporated with Dithiol Organic Anchors for Multiple Pollutants Capturing in Wastewater [J].
He, Hai-Bo ;
Li, Bin ;
Dong, Jun-Ping ;
Lei, Yun-Yi ;
Wang, Tian-Lin ;
Yu, Qiong-Wei ;
Feng, Yu-Qi ;
Sun, You-Bao .
ACS APPLIED MATERIALS & INTERFACES, 2013, 5 (16) :8058-8066
[22]   Facile synthesis of a boronate affinity sorbent from mesoporous nanomagnetic polyhedral oligomeric silsesquioxanes composite and its application for enrichment of catecholamines in human urine [J].
He, Haibo ;
Zhou, Ziqing ;
Dong, Chen ;
Wang, Xin ;
Yu, Qiong-wei ;
Lei, Yunyi ;
Luo, Liqiang ;
Feng, Yuqi .
ANALYTICA CHIMICA ACTA, 2016, 944 :1-13
[23]  
Hoogenboom R, 2014, WOODHEAD PUBL MATER, P15, DOI 10.1533/9780857097026.1.15
[24]   Metal-Organic Frameworks in Biomedicine [J].
Horcajada, Patricia ;
Gref, Ruxandra ;
Baati, Tarek ;
Allan, Phoebe K. ;
Maurin, Guillaume ;
Couvreur, Patrick ;
Ferey, Gerard ;
Morris, Russell E. ;
Serre, Christian .
CHEMICAL REVIEWS, 2012, 112 (02) :1232-1268
[25]   Size-controlled synthesis of nickel nanoparticles [J].
Hou, Y ;
Kondoh, H ;
Ohta, T ;
Gao, S .
APPLIED SURFACE SCIENCE, 2005, 241 (1-2) :218-222
[26]   Metal-organic frameworks [J].
James, SL .
CHEMICAL SOCIETY REVIEWS, 2003, 32 (05) :276-288
[27]   From fundamentals to applications: a toolbox for robust and multifunctional MOF materials [J].
Kirchon, Angelo ;
Feng, Liang ;
Drake, Hannah F. ;
Joseph, Elizabeth A. ;
Zhou, Hong-Cai .
CHEMICAL SOCIETY REVIEWS, 2018, 47 (23) :8611-8638
[28]   Metallo-supramolecular materials based on terpyridine-functionalized polyhedral silsesquioxane [J].
Koytepe, Sueleyman ;
Demirel, Maruf Hursit ;
Gultek, Ahmet ;
Seckin, Turgay .
POLYMER INTERNATIONAL, 2014, 63 (04) :778-787
[29]  
Kruglyak, 1982, XRAY METHOD ANAL POL
[30]   Smart polymers: Physical forms and bioengineering applications [J].
Kumar, Ashok ;
Srivastava, Akshay ;
Galaev, Igor Yu ;
Mattiasson, Bo .
PROGRESS IN POLYMER SCIENCE, 2007, 32 (10) :1205-1237