Origin of surface conductivity in diamond

被引:858
作者
Maier, F [1 ]
Riedel, M [1 ]
Mantel, B [1 ]
Ristein, J [1 ]
Ley, L [1 ]
机构
[1] Univ Erlangen Nurnberg, Phys Tech Inst, D-91058 Erlangen, Germany
关键词
D O I
10.1103/PhysRevLett.85.3472
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Hydrogen-terminated diamond exhibits a high surface conductivity (SC) that is commonly attributed to the direct action of hydrogen-related accepters. We give experimental evidence that hydrogen is only a necessary requirement for SC; exposure to air is also essential. We propose a mechanism in which a redox reaction in an adsorbed water layer provides the electron sink for the subsurface hole accumulation layer. The model explains the experimental findings including the fact that hydrogenated diamond is unique among all semiconductors in this respect.
引用
收藏
页码:3472 / 3475
页数:4
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