MoFeCrTiWAlNb refractory high-entropy alloy coating fabricated by rectangular-spot laser cladding

被引:83
作者
Guo, Yaxiong [1 ]
Liu, Qibin [1 ,2 ]
机构
[1] Guizhou Univ, Coll Mat & Met, Guiyang 550025, Guizhou, Peoples R China
[2] Guizhou Prov Key Lab Mat Struct & Strength, Guiyang 550025, Guizhou, Peoples R China
基金
中国国家自然科学基金;
关键词
MoFeCrTiWAINlb; Refractory high-entropy alloy; laser cladding; Coating; Wear resistance; MECHANICAL-PROPERTIES; MICROSTRUCTURE; BEHAVIOR; TIN; WEAR; AL2O3; STEEL;
D O I
10.1016/j.intermet.2018.09.005
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In order to improve the wear resistance of M2 tool steel, a MoFeCrTiWAINb high-entropy alloy (HEA) coating has been successfully fabricated by the rectangular-spot laser-cladding technique. The phase structures, microstructure, hardness, and wear resistance of HEA coatings were carefully investigated. The final laser-cladding process parameters are P = 3.0 kW, v = 4 mm/s, and a rectangular spot of 10 x 2 mm. The phase composition of the coating consists of body-centered-cubic solid solution and (Nb,Ti)C carbides plus small amounts of hexagonal-close-packed Fe2Nb phases. The coating metallurgically bonds to the substrate. Al2O3 formed by oxidization of Al atoms was a heterogenous nuclear center for (Nb,Ti)C. The highest average microhardness value of HEA coatings reached 1050 HV0.2, which is far higher than that of the substrate (approximately 330 HV0.2). Furthermore, compared with the substrate, the HEA coating exhibits prominent wear resistance with lower friction coefficient, fewer wear volumes, and smoother worn surface under the same conditions.
引用
收藏
页码:78 / 87
页数:10
相关论文
共 29 条
[1]  
[Anonymous], 2017, Intell Autom Soft Comput, DOI DOI 10.1080/10798587.2016.1267245
[2]   Fiber laser cladding of nickel-based alloy on cast iron [J].
Arias-Gonzalez, F. ;
del Val, J. ;
Comesana, R. ;
Penide, J. ;
Lusquinos, F. ;
Quintero, F. ;
Riveiro, A. ;
Boutinguiza, M. ;
Pou, J. .
APPLIED SURFACE SCIENCE, 2016, 374 :197-205
[3]   The effect of TiC/Al2O3 composite ceramic reinforcement on tribological behavior of laser cladding Ni60 alloys coatings [J].
Cai, Yangchuan ;
Luo, Zhen ;
Feng, Mengnan ;
Liu, Zuming ;
Huang, Zunyue ;
Zeng, Yida .
SURFACE & COATINGS TECHNOLOGY, 2016, 291 :222-229
[4]   Structure and properties of the TiN and Ti(C,N) coatings deposited in the PVD process on high-speed steels [J].
Dobrzanski, LA ;
Adamiak, M .
JOURNAL OF MATERIALS PROCESSING TECHNOLOGY, 2003, 133 (1-2) :50-62
[5]   Comparison of mechanical behavior of TiN, TiNC, CrN/TiNC, TiN/TiNC films on 9Cr18 steel by PVD [J].
Feng, Xingguo ;
Zhang, Yanshuai ;
Hu, Hanjun ;
Zheng, Yugang ;
Zhang, Kaifeng ;
Zhou, Hui .
APPLIED SURFACE SCIENCE, 2017, 422 :266-272
[6]   Microstructure and strengthening mechanisms in an FCC structured single-phase nanocrystalline Co25Ni25Fe25Al7.5Cu17.5 high-entropy alloy [J].
Fu, Zhiqiang ;
Chen, Weiping ;
Wen, Haiming ;
Zhang, Dalong ;
Chen, Zhen ;
Zheng, Baolong ;
Zhou, Yizhang ;
Lavernia, Enrique J. .
ACTA MATERIALIA, 2016, 107 :59-71
[7]   Microstructure and properties of in-situ TiN reinforced laser cladding CoCr2FeNiTix high-entropy alloy composite coatings [J].
Guo, Yaxiong ;
Shang, Xiaojuan ;
Liu, Qibin .
SURFACE & COATINGS TECHNOLOGY, 2018, 344 :353-358
[8]   Effect of Ti additions on mechanical properties of NbMoTaW and VNbMoTaW refractory high entropy alloys [J].
Han, Z. D. ;
Chen, N. ;
Zhao, S. F. ;
Fan, L. W. ;
Yang, G. N. ;
Shao, Y. ;
Yao, K. F. .
INTERMETALLICS, 2017, 84 :153-157
[9]   Dry sliding wear behavior of laser clad TiVCrAlSi high entropy alloy coatings on Ti-6Al-4V substrate [J].
Huang, Can ;
Zhang, Yongzhong ;
Vilar, Rui ;
Shen, Jianyun .
MATERIALS & DESIGN, 2012, 41 :338-343
[10]   Thermal stability and oxidation resistance of laser clad TiVCrAlSi high entropy alloy coatings on Ti-6A1-4V alloy [J].
Huang, Can ;
Zhang, Yongzhong ;
Shen, Jianyun ;
Vilar, Rui .
SURFACE & COATINGS TECHNOLOGY, 2011, 206 (06) :1389-1395