Influence of Ring Structures on Optical Properties of Trivalent Bismuth in Bi-Doped Silica Optical Fiber

被引：10

作者：

Jia, Baonan ^{[1
]}

Lu, Pengfei ^{[1
]}

Zhang, Jie ^{[1
]}

Peng, Zhixing ^{[1
]}

Yan, Binbin ^{[1
]}

Wang, You ^{[2
]}

Peng, Gang-Ding ^{[3
]}

机构：

[1] Beijing Univ Posts & Telecommun, State Key Lab Informat Photon & Opt Commun, Minist Educ, Beijing 100876, Peoples R China

[2] Southwest Inst Tech Phys, Chengdu 610041, Peoples R China

[3] Univ New South Wales, Sch Elect Engn & Telecommun, Sydney, NSW 2052, Australia

来源：

JOURNAL OF CLUSTER SCIENCE | 2018年 / 29卷 / 05期

关键词：

First-principles calculation; Optical fiber; Frontier molecular orbital; Absorption and emission spectra; BROAD-BAND EMISSION; INFRARED LUMINESCENCE; GERMANATE GLASS; CENTERS; LEAD; PHOTOLUMINESCENCE;

D O I：

10.1007/s10876-018-1362-x

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We report silica fiber with trivalent bismuth (Bi3+) in first-principles calculations. The influences of members of "Si-O-Si" rings are considered to study atomic structures, frontier molecular orbital and optical properties of Bi-doped optical fiber. Our results reveal that the luminescence of Bi3+-doped optical fiber is the result of a combination of Bi3+ ions and silica matrix. Different ring structures affect the luminescence properties, which explained why Bi3+-doped silica fiber usually cover a broad spectral range from the UV to visible light.

引用

页码：861 / 865

页数：5

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