Influence of Ring Structures on Optical Properties of Trivalent Bismuth in Bi-Doped Silica Optical Fiber

被引:10
作者
Jia, Baonan [1 ]
Lu, Pengfei [1 ]
Zhang, Jie [1 ]
Peng, Zhixing [1 ]
Yan, Binbin [1 ]
Wang, You [2 ]
Peng, Gang-Ding [3 ]
机构
[1] Beijing Univ Posts & Telecommun, State Key Lab Informat Photon & Opt Commun, Minist Educ, Beijing 100876, Peoples R China
[2] Southwest Inst Tech Phys, Chengdu 610041, Peoples R China
[3] Univ New South Wales, Sch Elect Engn & Telecommun, Sydney, NSW 2052, Australia
关键词
First-principles calculation; Optical fiber; Frontier molecular orbital; Absorption and emission spectra; BROAD-BAND EMISSION; INFRARED LUMINESCENCE; GERMANATE GLASS; CENTERS; LEAD; PHOTOLUMINESCENCE;
D O I
10.1007/s10876-018-1362-x
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
We report silica fiber with trivalent bismuth (Bi3+) in first-principles calculations. The influences of members of "Si-O-Si" rings are considered to study atomic structures, frontier molecular orbital and optical properties of Bi-doped optical fiber. Our results reveal that the luminescence of Bi3+-doped optical fiber is the result of a combination of Bi3+ ions and silica matrix. Different ring structures affect the luminescence properties, which explained why Bi3+-doped silica fiber usually cover a broad spectral range from the UV to visible light.
引用
收藏
页码:861 / 865
页数:5
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