Micellar and vesicular nanoassemblies of triazole-based amphiphilic probes triggered by mercury(II) ions in a 100% aqueous medium

被引:22
作者
Kim, Inhye [1 ]
Lee, Na-Eun [1 ]
Jeong, Yoo-Jeong [1 ]
Chung, Young-Ho [2 ]
Cho, Byoung-Ki [3 ]
Lee, Eunji [1 ,2 ]
机构
[1] Chungnam Natl Univ, Grad Sch Analyt Sci & Technol, Taejon 305764, South Korea
[2] Korea Basic Sci Inst, Div Life Sci, Taejon 305806, South Korea
[3] Dankook Univ, Dept Chem, Gyeonggi Do 448701, South Korea
基金
新加坡国家研究基金会;
关键词
BLOCK-COPOLYMERS; CLICK REACTION; FLUORESCENT; SENSOR; TRANSITION; CHEMOSENSORS; SYSTEMS;
D O I
10.1039/c4cc06742h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
ABA-type amphiphiles bearing a triazole-based aromatic block were easily synthesized using click chemistry, which act as fluorescent turn-off Hg2+-chemoprobes in an aqueous solution. Interestingly, the metal-binding process of amphiphiles induced nanoassemblies even below the CMCs, and the binding stoichiometry affected the morphologies of the resultant nanostructures.
引用
收藏
页码:14006 / 14009
页数:4
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