Photolabile Well-Defined Polystyrene Grafted on Silica Nanoparticle via Nitroxide-Mediated Polymerization (NMP)

被引：6
作者：
Ho, Hien The [1 ,2 ]
Phan, Trang N. T. [1 ]
Bonnevide, Marine [3 ]
Malicki, Nicolas [3 ]
Couty, Marc [3 ]
Jestin, Jacques [2 ]
Gigmes, Didier [1 ]
机构：
[1] Aix Marseille Univ, CNRS, Inst Chim Radicalaire, Ave Escadrille Normandie Niemen, Marseille, France
[2] Univ Paris Saclay, Lab Leon Brillouin, CEA Saclay, F-91191 Gif Sur Yvette, France
[3] Mfg Francaise Pneumat MICHELIN, Site Ladoux, 23 Pl Carmes Dechaux, F-63040 Clermont Ferrand 9, France
来源：
MACROMOLECULAR RAPID COMMUNICATIONS | 2021年 / 42卷 / 18期
关键词：
photoresponsive materials; polymer-grafted silica nanoparticles; surface-initiated nitroxide-mediated polymerization; SURFACE; NANOCOMPOSITES; OPPORTUNITIES; DELIVERY; POLYMERS; BRUSHES; RELEASE;
D O I：
10.1002/marc.202100181
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Herein, the synthesis of a novel nitroxide-mediated polymerization (NMP) initiator bearing a photolabile ortho-nitrobenzyl (oNB) group allowing surface-initiated NMP preparation of well-defined photoresponsive polystyrene grafted on silica nanoparticles is described. The photocleavable and photoresponsive properties of the prepared materials are demonstrated using small angle X-ray scattering (SAXS) characterization.
引用
收藏
页数：5
相关论文
共 26 条
[1]   PHOTOSENSITIVE PROTECTIVE GROUPS [J].
BARLTROP, JA ;
PLANT, PJ ;
SCHOFIELD, P .
CHEMICAL COMMUNICATIONS, 1966, (22) :822-+
[2]   Photolabile protecting groups and linkers [J].
Bochet, CG .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 2002, (02) :125-142
[3]   Synthesis of polyisoprene, polybutadiene and Styrene Butadiene Rubber grafted silica nanoparticles by nitroxide-mediated polymerization [J].
Bonnevide, Marine ;
Phan, Trang N. T. ;
Malicki, Nicolas ;
Kumar, Sanat K. ;
Couty, Marc ;
Gigmes, Didier ;
Jestin, Jacques .
POLYMER, 2020, 190
[4]   Morphologies of Polyisoprene-Grafted Silica Nanoparticles in Model Elastomers [J].
Bonnevide, Marine ;
Jimenez, Andrew M. ;
Dhara, Deboleena ;
Phan, Trang N. T. ;
Malicki, Nicolas ;
Abbas, Zaid M. ;
Benicewicz, Brian ;
Kumar, Sanat K. ;
Couty, Marc ;
Gigmes, Didier ;
Jestin, Jacques .
MACROMOLECULES, 2019, 52 (20) :7638-7645
[5]   PHOTOGENERATION OF ORGANIC-BASES FROM ORTHO-NITROBENZYL-DERIVED CARBAMATES [J].
CAMERON, JF ;
FRECHET, JMJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (11) :4303-4313
[6]   Polystyrene grafting from silica nanoparticles via nitroxide-mediated polymerization (NMP): synthesis and SANS analysis with the contrast variation method [J].
Chevigny, Chloe ;
Gigmes, Didier ;
Bertin, Denis ;
Jestin, Jacques ;
Boue, Francois .
SOFT MATTER, 2009, 5 (19) :3741-3753
[7]   A photochemical approach for controlled drug release in targeted drug delivery [J].
Choi, Seok Ki ;
Verma, Manisha ;
Silpe, Justin ;
Moody, Ryan E. ;
Tang, Kenny ;
Hanson, Jeffrey J. ;
Baker, James R., Jr. .
BIOORGANIC & MEDICINAL CHEMISTRY, 2012, 20 (03) :1281-1290
[8]   Surface-initiated nitroxide-mediated polymerization:: a tool for hybrid inorganic/organic nanocomposites 'in situ' synthesis [J].
Ghannam, Leila ;
Parvole, Julien ;
Laruelle, Gael ;
Francois, Jeanne ;
Billon, Laurent .
POLYMER INTERNATIONAL, 2006, 55 (10) :1199-1207
[9]   Photo-responsive block copolymer micelles: design and behavior [J].
Gohy, Jean-Francois ;
Zhao, Yue .
CHEMICAL SOCIETY REVIEWS, 2013, 42 (17) :7117-7129
[10]  
Green MD, 2014, POLYM CHEM-UK, V5, P5535, DOI [10.1039/c4py00638k, 10.1039/C4PY00638K]
123