Epoxidation catalyzed by iron(III) and mangahese(III) pyridine-2-carboxamido complexes

被引：19

作者：

Yang, Li

Wei, Rui-Ning

Li, Rui

Zhou, Xiang-Ge ^{[1
]}

Zuo, Jing-Lin

机构：

[1] Sichuan Univ, Coll Chem, Inst Homogeneous Catalysis, Chengdu 610064, Peoples R China

[2] Yibin Univ, Dept Chem Engn, Yibin 644000, Peoples R China

[3] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2007年 / 266卷 / 1-2期

基金：

中国国家自然科学基金;

关键词：

pyridine-2-carboxamido; iron; manganese; catalytic epoxidation; ASYMMETRIC EPOXIDATION; UNFUNCTIONALIZED OLEFINS; CRYSTAL-STRUCTURES; LIGAND; MANGANESE; ALKENES; IRON; METALLOPHTHALOCYANINES; COORDINATION; CHEMISTRY;

D O I：

10.1016/j.molcata.2006.11.015

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A series of Fe(III) and Mn(III) complexes containing N-4 non-porphyrin pyridine-2-carboxamido ligands have been synthesized. Their catalytic abilities in epoxidation and the effects of reaction conditions such as temperature, solvent have been studied, leading to the highest yield of 92% for 4-methoxystyrene by using [Mn(bbpc)Cl(DMF)] (H(2)bbpc = 1,2-bis(4'-tert-butylpyridine-2'-carboxarnido)-4,5-dichlorobenzene) as catalyst. (c) 2006 Elsevier B.V. All rights reserved.

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收藏

页码：284 / 289

页数：6

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