Connecting structure and dynamics in glass forming materials by photon correlation spectroscopy

被引:24
作者
Sidebottom, D. L. [1 ]
Rodenburg, B. V. [1 ]
Changstrom, J. R. [1 ]
机构
[1] Creighton Univ, Dept Phys, Omaha, NE 68178 USA
关键词
LIGHT-SCATTERING; BRILLOUIN-SCATTERING; SUPERCOOLED LIQUIDS; RELAXATION; TRANSITION; FRAGILITY; CAKNO3; TIME;
D O I
10.1103/PhysRevB.75.132201
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We report photon correlation spectroscopy measurements of the alpha-relaxation in a series of glass forming liquids of widely varying fragility and demonstrate a correlation between the nonergodic level of the liquid and its fragility. This correlation, when combined with a previous correlation established between fragility and the stretching exponent that characterizes the nonexponentiality of the alpha-relaxation, implies that the alpha-relaxation should, in general, conform to scaling that is described by just two parameters: the nonergodic level and the glass transition temperature.
引用
收藏
页数:4
相关论文
共 29 条
[1]   RELAXATION IN LIQUIDS, POLYMERS AND PLASTIC CRYSTALS - STRONG FRAGILE PATTERNS AND PROBLEMS [J].
ANGELL, CA .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1991, 131 :13-31
[2]   NONEXPONENTIAL RELAXATIONS IN STRONG AND FRAGILE GLASS FORMERS [J].
BOHMER, R ;
NGAI, KL ;
ANGELL, CA ;
PLAZEK, DJ .
JOURNAL OF CHEMICAL PHYSICS, 1993, 99 (05) :4201-4209
[3]   Does the interaction potential determine both the fragility of a liquid and the vibrational properties of its glassy state? [J].
Bordat, P ;
Affouard, F ;
Descamps, M ;
Ngai, KL .
PHYSICAL REVIEW LETTERS, 2004, 93 (10) :105502-1
[4]   Fragility and compressibility at the glass transition [J].
Buchenau, U ;
Wischnewski, A .
PHYSICAL REVIEW B, 2004, 70 (09) :092201-1
[5]   Supercooled liquids and the glass transition [J].
Debenedetti, PG ;
Stillinger, FH .
NATURE, 2001, 410 (6825) :259-267
[6]   BRILLOUIN-SCATTERING IN SALOL - DETERMINING T(C) OF THE MODE-COUPLING THEORY [J].
DREYFUS, C ;
LEBON, MJ ;
CUMMINS, HZ ;
TOULOUSE, J ;
BONELLO, B ;
PICK, RM .
PHYSICAL REVIEW LETTERS, 1992, 69 (25) :3666-3669
[7]   Supercooled liquids and glasses [J].
Ediger, MD ;
Angell, CA ;
Nagel, SR .
JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (31) :13200-13212
[8]  
Ford N C., 1985, Dynamic Light Scattering: Applications of Photon Correlation Spectroscopy, P7
[9]   Asymptotic laws and preasymptotic correction formulas for the relaxation near glass-transition singularities [J].
Franosch, T ;
Fuchs, M ;
Gotze, W ;
Mayr, MR ;
Singh, AP .
PHYSICAL REVIEW E, 1997, 55 (06) :7153-7176
[10]   PRIMARY RELAXATION IN A HARD-SPHERE SYSTEM [J].
FUCHS, M ;
HOFACKER, I ;
LATZ, A .
PHYSICAL REVIEW A, 1992, 45 (02) :898-912