Evolution of the surface chemistry of hot dip galvanized Zn-Mg-Al and Zn coatings on steel during short term exposure to sodium chloride containing environments

被引：70

作者：

Duchoslav, J. ^{[1
]}

Steinberger, R. ^{[1
]}

Arndt, M. ^{[1
]}

Keppert, T. ^{[2
]}

Luckeneder, G. ^{[2
]}

Stellnberger, K. H. ^{[2
]}

Hagler, J. ^{[2
]}

Angeli, G. ^{[2
]}

Riener, C. K. ^{[2
]}

Stifter, D. ^{[1
]}

机构：

[1] Johannes Kepler Univ Linz, Ctr Surface & Nanoanalyt, Christian Doppler Lab Microscop & Spectroscop Mat, A-4040 Linz, Austria

[2] Voestalpine Stahl GmbH, A-4031 Linz, Austria

来源：

CORROSION SCIENCE | 2015年 / 91卷

关键词：

Metal coatings; Zinc; XPS; Atmospheric corrosion; X-RAY PHOTOELECTRON; COATED STEEL; CORROSION-RESISTANCE; ATMOSPHERIC CORROSION; ZINC; MAGNESIUM; PRODUCTS; SPECTROSCOPY; XPS; DISSOLUTION;

D O I：

10.1016/j.corsci.2014.11.033

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

In the current study, the evolution of corrosion products on the surfaces of hot-dip galvanized Zn-Mg-Al and standard Zn coatings during short term exposure to standardized salt spray test was investigated by X-ray photoelectron spectroscopy. The obtained results demonstrated a rapid formation of double layered hydroxides (DLH) covering the surface of the Zn-Mg-Al coatings. The DLH surface layer was found to stabilize the surface pH and hinder further surface alkalization as observed for the Zn coatings and indicated by the occurrence of Na2CO3. As a consequence, the progress of Zn-Mg-Al corrosion was slowed down, but not completely stopped. (C) 2014 Elsevier Ltd. All rights reserved.

引用

页码：311 / 320

页数：10

共 41 条

[1]

[Anonymous], 9227200610 DIN EN IS

[2] Nanoscale analysis of surface oxides on ZnMgAl hot-dip-coated steel sheets [J].

Arndt, M. ;

Duchoslav, J. ;

Itani, H. ;

Hesser, G. ;

Riener, C. K. ;

Angeli, G. ;

Preis, K. ;

Stifter, D. ;

Hingerl, K. .

ANALYTICAL AND BIOANALYTICAL CHEMISTRY, 2012, 403 (03) :651-661

[3] Corrosion mechanisms of Zn(Mg,Al) coated steel: 2. The effect of Mg and Al alloying on the formation and properties of corrosion products in different electrolytes [J].

Azevedo, M. Salgueiro ;

Allely, C. ;

Ogle, K. ;

Volovitch, P. .

CORROSION SCIENCE, 2015, 90 :482-490

[4] Corrosion mechanisms of Zn(Mg, Al) coated steel in accelerated tests and natural exposure: 1. The role of electrolyte composition in the nature of corrosion products and relative corrosion rate [J].

Azevedo, M. Salgueiro ;

Allely, C. ;

Ogle, K. ;

Volovitch, P. .

CORROSION SCIENCE, 2015, 90 :472-481

[5] HYDROTALCITE-TYPE ANIONIC CLAYS: PREPARATION, PROPERTIES AND APPLICATIONS [J].

Cavani, F. ;

Trifiro, F. ;

Vaccari, A. .

CATALYSIS TODAY, 1991, 11 (02) :173-301

[6] Microstructural characterization and quantification of Zn-Al-Mg surface coatings [J].

Commenda, C. ;

Puehringer, J. .

MATERIALS CHARACTERIZATION, 2010, 61 (10) :943-951

[7] Initial formation of corrosion products on pure zinc and MgZn2 examinated by XPS [J].

Diler, E. ;

Lescop, B. ;

Rioual, S. ;

Vien, G. Nguyen ;

Thierry, D. ;

Rouvellou, B. .

CORROSION SCIENCE, 2014, 79 :83-88

[8] Chemistry of corrosion products of Zn and MgZn pure phases under atmospheric conditions [J].

Diler, E. ;

Rioual, S. ;

Lescop, B. ;

Thierry, D. ;

Rouvellou, B. .

CORROSION SCIENCE, 2012, 65 :178-186

[9] Nanoscopic view on the initial stages of corrosion of hot dip galvanized Zn-Mg-Al coatings [J].

Duchoslav, J. ;

Arndt, M. ;

Steinberger, R. ;

Keppert, T. ;

Luckeneder, G. ;

Stellnberger, K. H. ;

Hagler, J. ;

Riener, C. K. ;

Angeli, G. ;

Stifter, D. .

CORROSION SCIENCE, 2014, 83 :327-334

[10] XPS investigation on the surface chemistry of corrosion products on ZnMgAl-coated steel [J].

Duchoslav, J. ;

Arndt, M. ;

Keppert, T. ;

Luckeneder, G. ;

Stifter, D. .

ANALYTICAL AND BIOANALYTICAL CHEMISTRY, 2013, 405 (22) :7133-7144

← 1 2 3 4 5 →