Solvation studies of dimethylsulfoxide in non-aqueous solvents at high temperatures and at an atmospheric pressure

被引:0
作者
Kaur, Manpreet [1 ]
机构
[1] Dept Chem, DAV 10, Chandigarh 160011, India
来源
INDIAN JOURNAL OF CHEMISTRY | 2022年 / 61卷 / 02期
关键词
Density; Viscosity; Ultrasonic Velocity; Non-aqueous solvents; Acoustic parameters; BINARY-MIXTURES; ULTRASONIC VELOCITY; DIMETHYL-SULFOXIDE; EXCESS PROPERTIES; ETHYLENE-GLYCOL; VISCOSITY; NITROMETHANE; DENSITY; VOLUMES; WATER;
D O I
暂无
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Solvation studies of pure non aqueous liquids like dimethylsulfoxide, pyridine and nitromethane and their binary mixtures have been measured at 0, 20, 40, 60, 80 and 100 mol% of pyridine and nitromethane at 298 K, 308 K and 318 K temperatures. Density, viscosity and ultrasonic velocities of the solvents have been measured. From the measured data, the isentropic compressibility and acoustic parameters like acoustic impedance, free volume, intermolecular free length, internal pressure, Gibb's free energy, relaxation time, Rao's constant, absorption coefficient, Wada's constant, and entropy are calculated using experimental velocities, viscosities and densities at three different temperatures (298 K, 308 K and 318 K) and 1 atm pressure.
引用
收藏
页码:144 / 153
页数:10
相关论文
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