Synthesis and crystal structure of [Pb(phe)2]n:: a 2D coordination polymer of lead(II) containing phenylalanine

被引：17
作者：
Marandi, Farzin [1 ]
Shahbakhsh, Nahid
机构：
[1] Payam Noor Univ Zanjan, Dept Sci, Zanjan, Iran
[2] Zanjan Univ, Dept Chem, Zanjan, Iran
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2007年 / 633卷 / 08期
关键词：
phenylalanine; lead; crystal structure;
D O I：
10.1002/zaac.200700113
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
[Pb(phC)(2)](n), (1) (phe is the abbreviation ofphenylalanine) have been synthesized and characterized by elemental analyses, IR and 'H NMR spectroscopy. The single crystal structure of 1 show the complex to be a 2D chain polymer as a result of phenylalanine bridging. Coordination number of Pb-II ions is six, PbN2O4, with "stereo-chemically active" electron lone pairs, and the coordination sphere is hemidirected. To the best of our knowledge, this 2D coordination polymer is the first amino acid lead(II) complex that characterized by X-ray structural analysis.
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收藏
页码：1137 / 1139
页数：3
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