Silica sulfuric acid promoted selective oxidation of sulfides to sulfoxides or sulfones in the presence of aqueous H2O2

被引：140

作者：

Shaabani, Ahmad ^{[1
]}

Rezayan, Ali Hossein ^{[1
]}

机构：

[1] Shahid Beheshti Univ Med Sci, Dept Chem, Tehran, Iran

来源：

CATALYSIS COMMUNICATIONS | 2007年 / 8卷 / 07期

关键词：

oxidation; sulfide; sulfoxide; sulfone; hydrogen peroxide; silica sulfuric acid;

D O I：

10.1016/j.catcom.2006.10.033

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Alkyl and aryl sulfides are oxidized to the corresponding sulfoxides or sulfones in excellent yields with aqueous hydrogen peroxide in the presence of silica sulfuric acid as an efficient solid acid catalyst. The oxidation of alkyl and aryl sulfide proceeds at 25-90 degrees C and the corresponding sulfoxides or sulfones was selectively obtained by controlling the amounts of H2O2 and catalyst. (C) 2006 Elsevier B.V. All rights reserved.

引用

页码：1112 / 1116

页数：5

共 50 条

[1] [Anonymous], 1989, HDB CHEM PHYS, V69th
[2] Oxidations of benzyl and phenethyl phenyl sulfides. Implications for the mechanism of the microsomal and biomimetic oxidation of sulfides
Baciocchi, E
Lanzalunga, O
Pirozzi, B
[J]. TETRAHEDRON, 1997, 53 (36) : 12287 - 12298
[3] Oxidation of sulfides by peroxidases. Involvement of radical cations and the rate of the oxygen rebound step
Baciocchi, E
Lanzalunga, O
Malandrucco, S
Ioele, M
Steenken, S
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (37) : 8973 - 8974
[4] Selective oxidation of sulfides to sulfoxides and sulfones using hydrogen peroxide (H2O2) in the presence of zirconium tetrachloride
Bahrami, K
[J]. TETRAHEDRON LETTERS, 2006, 47 (12) : 2009 - 2012
[5] BERENGUER MR, Patent No. 1270555
[6] METAL CATALYSIS IN OXIDATION BY PEROXIDES .21. SULFIDE OXIDATION AND OLEFIN EPOXIDATION BY DILUTE HYDROGEN-PEROXIDE CATALYZED BY MOLYBDENUM AND TUNGSTEN DERIVATIVES UNDER PHASE-TRANSFER CONDITIONS
BORTOLINI, O
DIFURIA, F
MODENA, G
SERAGLIA, R
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1985, 50 (15) : 2688 - 2690
[7] APPLICATIONS OF SULFOXIDES TO ASYMMETRIC-SYNTHESIS OF BIOLOGICALLY-ACTIVE COMPOUNDS
CARRENO, MC
[J]. CHEMICAL REVIEWS, 1995, 95 (06) : 1717 - 1760
[8] CHATTERJI AC, 1972, Z PHYS CHEM-LEIPZIG, V250, P137
[9] CHATTERJI AC, 1972, CHEM ABSTR, V77, P39201
[10] COTTON H, Patent No. 9925711

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