Hydrogen release from amminelithium borohydride, LiBH4•NH3

被引：110

作者：

Guo, Yanhui ^{[1
]}

Xia, Guanglin ^{[1
]}

Zhu, Yihan ^{[2
]}

Gao, Liang ^{[1
]}

Yu, Xuebin ^{[1
]}

机构：

[1] Fudan Univ, Dept Mat Sci, Shanghai 200433, Peoples R China

[2] Zhejiang Univ, Inst Catalysis, Hangzhou 310000, Zhejiang, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 15期

关键词：

AMMONIA BORANE; LITHIUM BOROHYDRIDE; STORAGE; COMPLEX; CAPACITY;

D O I：

10.1039/b924057h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Amminelithium borohydride, LiBH4 center dot NH3 which has two temperature sensitive chemical bonds N:-> Li+ and N-H center dot center dot center dot H-B, is shown to release hydrogen at low temperatures by stabilizing the ammonia and promoting the recombination of the NH center dot center dot center dot HB bond.

引用

页码：2599 / 2601

页数：3

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